93rd Canadian Chemistry Conference and Exhibition

Sunday PM

AN4Room 201 C

Electrochemistry and Electrocatalysis (joint with SS1)

Organizer(s) - Gregory Jerkiewicz; Michael Eikerling

13:40 00261 Electrocatalysis on Metallic Nanotubes and Nanowires $Ponrouch A., Garbarino S., *Guay D.
14:20 00262 Electrochemical Activity of Pd-based Nanomaterials for Oxygen Reduction Reaction in Alkaline Medium $Diabate D., Habrioux A., Servat K., Kokoh B.K., *Napporn T.W.
14:40 00263 Optimizing Conjugated Polymer Composites for Electronic Applications *Freund M.S., Rahman G.M.A., Zhao J.H., Thomson D.J.
15:00 00264 Probing Charge Transport through Aryl Films on Carbon with Conducing Probe AFM *$McDermott M.T., Chisholm R., McCreery R.L., Bergren A.J.
15:20 00265 Electron-Transfer Kinetics at a Pencil Lead Electrode *$Kariuki J.K., Friend J., King D.
15:40 Coffee Break
16:00 00266 Electroactivity of Gold Platinum Nanoparticles Towards CO Oxidation in Alkaline Medium *Kokoh K.B., $Habrioux A., Napporn T.W., Servat K.
16:40 00267 A Comparative Study of Electrochemical Techniques in Investigating the Adsorption Behaviour of Fibrinogen on Platinum Farcas M., Cosman N.P., Ting D.K., Roscoe S.G., Omanovic S.
17:00 00268 Effect of Electrode Position on Features of Electrochemical Polarization Modulation Infrared Reflection Absorption Spectroscopy (PM IRRAS) *$Zamlynny V., Blatt S., Roscoe S.G.
17:20 00269 Scanning Electrochemical Microscopy Approach Curves for Ring Microelectrodes in Pure Negative and Positive Feedback Mode Cornut R., Mayoral M., Fabre D., *Mauzeroll J.
17:40 00270 In Situ Observation of the Mechanism and Dynamics of Bismuth Electrodeposition by Video STM Lin E., Matsushima H., Zheng S., *Morin S., Magnussen O.M.
18:00 End of Session

AN6Room 201 F


Organizer(s) - Michael Thompson

14:20 00271 A Fragmentation Study of the Rhodamine 610 Cation using Visible-MALDI Yang C.Y., Hu X.H., Loboda A.V., *$Lipson R.H.
14:40 00272 Development of a Novel Gallium and Indium-selective Bulk Optode Membrane Based on Kryptofix and 1-(2-pyridylazo)-2-naphtol *Ghafourifar G., $Jabbari A., Alizadeh Motlagh N.
Maxxam Award Lecture

15:00 00273 Advances in the Analysis of Persistent Halogenated Organic Compounds Reiner E.J., Boden A.R., Muscalu A.M., Chen T., MacPherson K.A.
15:40 Coffee Break
16:00 00274 Stable Micron-length Liquid Spreading with an Open Interface for Downstream Applications: Revisiting the Role of Surface Roughness in Wettability Zarrine-Afsar A., Müller C., Talbot F.O., Paarmann A., *$Miller R.J.D.
16:20 00275 Langmuir-Blodgett Monolayers of Phospholipids. Surface Enhanced Raman Scattering on Nanostructured Silver Films *Moula G., $Aroca R.
16:40 00276 Production, Detection, and Separation of Naturally Occurring Nisin Variants from Lactic Acid Bacteria Donkor K.K., Kellock T.T., Van Hamme J.D., Soliman L.C.
17:00 00277 Model of Droplet Motion under a Single Pressure Source Control Glawdel T., Elbuken C., Ren C.
17:20 End of Session

BM3Room 203 A

Bioorganic Chemistry (A Symposium Celebrating Ron Kluger's 65th Birthday)

Organizer(s) - Andrew Woolley
Chair(s) - A. Woolley

13:40 00278 Selective Neuronal Nitric Oxide Synthase Inhibitors for the Prevention and Treatment of Neurodegenerative Diseases *$Silverman R.B.
14:20 00279 Hydrogen Bonds in Synthesis, Molecular Recognition and Catalysis *$Chin J., Kim H., Mui L., So S.
14:40 00280 Organosulfates: Their Synthesis and the Enzymes that Process Them *$Taylor S.D.
15:00 00281 Measurement of Kinetic Isotope Effects on Sialidase Catalyzed-Hydrolysis Reactions with Natural Substrate Analogues Chan J., *Bennet A.J.
15:20 00282 Movement of Subtituents Around Stereocenters During Catalysis by Racemases and Epimerases *$Bearne S.L.
15:40 Coffee Break
Bernard Belleau Award Lecture

16:00 00283 Studies on, and the Manipulation of, Enzymes Involved in Alkaloid and Sialic Acid Biosynthetic Pathways Tanner M.E.
16:40 00284 Investigating the Structural Elements Leading to Efficient Dinuclear Zn(II) Complexes that Catalyze the Cleavage of Phosphate Diesters Mohamed M.F., Neverov A.A., $Brown R.S.
17:00 00285 Activity-based Proteome Profiling of Hepatitis C Virus Replication: Newly Discovered Roles of Host Cell Hydrolase Enzymes in the Viral Life Cycle* *$Pezacki J.P., Blais D.R., Singaravelu R., Qian Y., McKay C.S.
17:20 00286 It's So Hard to Let Go: Staged Product Release in the MurA Catalytic Mechanism *$Berti P.J., Jackson S.G., Chindemi P., Zhang F., Junop M.S.
17:40 00287 Accelerating Decarboxylation in Enzymic Intermediates - The Importance of Overcoming Internal Return of CO2 *$Kluger R., Mundle S.O.C.
18:00 End of Session

BM4Room 205 C

Cancer Therapeutics (joint with OR1)

Organizer(s) - Louise Edwards; David Uehling; Methvin Issac
Chair(s) - L. Edwards

13:40 00288 Developing Potent and Selective Inhibitors of Oncogenic STAT3 Function in Human Cancers *$Gunning P.T.
14:20 00289 SH2 Domain Proteomimetics as Potent Disruptors of a Clinically-Relevant Oncogenic Protein-Protein Interaction Drewry J.A., $Gunning P.T.
14:40 00290 A Peptidomimetic STAT3 Inhibitor Sensitizes Human Prostate Cancer Cells to Chemotherapeutic Treatment: A Promising Synergistic Combination Strategy Shahani V.M., Fletcher S., Sharmeen S., Sukhai M.A., Yue P., Luu D.P., Schimmer A.D., Turkson J., *$Gunning P.T.
15:00 00291 Designed Molecular Hybrids as Improved Anticancer Agents Gleason J.L.
15:20 00292 Direct Evidence of Formation Mechanism of the Self-Assembled Uniform-Size Unilamellar Liposomes for Delivery Carriers *$Nieh M.-P., Mahabir S., Wan W., Katsaras J.
15:40 Coffee Break
16:00 00293 6-Ethynylthieno[3,2-d]- and 6-Ethynylthieno[2,3-d]pyrimidin-4-anilines as Tunable Covalent Modifiers of ErbB Kinases Uehling D.E.
17:00 00295 Novel Inhibitors of Human Farnesyl Pyrophosphate Synthase; in Silico Design, Synthesis and Biological Evaluation *De Schutter J.W., $Tsantrizos Y.S.
17:20 00296 Design and Optimization of Effective Platinum(II)-based G-Quadruplex DNA Binders as Anticancer Therapeutics Castor K.J., *Kieltyka R., $Sleiman H.F.
17:40 00297 The Effect of Serum Protein Binding on the Reduction and Activity of Ruthenium(III) Anti-Cancer Agents Webb M.I., *$Walsby C.J.
18:00 End of Session

CE5Room 206 E

Teaching Writing Skills to Chemists

Organizer(s) - Leslie Barton
Chair(s) - A.P. Dicks; L. Barton

13:40 00298 Recording Experimental Work Barton L.
14:00 00299 Innovative Teaching Methods as Communication *$Kutas C.M.
14:20 00300 The Use of Discipline Specific, Writing-Intensive Learning as a Communication and Learning Tool in an Inorganic Chemistry Laboratory Course *Hanlan L., Alexander K.
14:40 00301 Teaching Discipline-Specific Writing to Chemical Engineering Undergraduates: A Reflective, Iterative Process *Ambidge C., Tihanyi D.
15:00 00302 Communicating Chemistry Gaede H.C.
15:40 Coffee Break
The Pearson Education Canada Lecture

16:00 00303 Writing as Thinking Kovac J.
16:40 00304 The WIT Project: Teaching Laboratory Writing Skills to Undergraduates at the University of Toronto Dicks A.P., Edgar L.J.
17:00 00305 Trading in the Backpack: Professional Development of Senior Year Chemistry Students Focsaneanu K.-S., Blake J.A.
17:20 00306 Teaching Writing to Chemistry Graduate Students- What They Learned, What We Learned *$Ilnicki-Stone E.I., Guenther S., Korcok D., Brindle J.
17:40 End of Session

EN5Room 201 B

Organic Matter in the Environment: Characterization, Reactivity, Formation

Organizer(s) - Jonathan Abbatt; Andre Simpson

13:40 Allen Robinson

14:40 00307 Formation of Highly Oxygenated Organics from Aqueous OH Radical Oxidation of Glyoxal: Implications for Secondary Organic Aerosol Formation Lee A.K. Y., *Abbatt J.P.D.
15:00 00308 Temporal Variations and Source Apportionment of Polycyclic Aromatic Hydrocarbons (PAH) Collected at a Sub-Arctic Site in Yukon, Canada Sofowote U.M., Rostogi A., *$McCarry B.E., Hung H., Westgate J.N., DeLuca P.
15:20 00309 The Elucidation of Molecular Interactions Between Organofluorides and Soil Organic Matter using 1H{19F} and 19F{1H} Heteronuclear Saturation Transfer Difference NMR Spectroscopy Longstaffe J.G., Simpson M.J., *$Simpson A.J.
15:40 Coffee Break
16:00 00310 Photochemical Transformation of Frozen Nitrate and Nitrite Solutions in the Presence of Model Organic Compounds Abida O., *Osthoff H.D., Sutherland T.C.
16:20 00311 The Kinetics of the Reactions of Cl With Some Cyclic Ethers *$Roscoe J.M., Giri B.R.
16:40 00312 Protection of Organic Matter from Chemical Attack via Interactions with Mineral Surfaces and Organic Matter Self Association Clemente J.S., Hills K., $Simpson M.J.
17:00 00313 Carbonaceous Aerosols at Whistler Peak *Leaitch W.R., Huang L., Ernst D., Macdonald A.M., Sharma S., Takahama S., Schwartz R.E., Russell L.M.
17:20 End of Session

IC2Room 203 B

Industry Emerging Technologies and Trends

Organizer(s) - Adrien Cote; Naveen Chopra
Chair(s) - A. Cote; N. Chopra

13:40 00314 Hydrogen Storage Materials Research at Ford Motor Company Sudik A., Yang J., Hirano S.
14:20 00315 Metal Organic Frameworks as CO2 Capture Materials and as Fuel Cell Electrolytes *$Shimizu G.K.H., Vaidhyanathan R., Hurd J.A., Iremonger S.S., Thangadurai V.
14:40 00316 Infrared Spectroscopy using Quantum Cascade Lasers Wang P., Tague T.J., Pflügl C., Diehl L., Witinski M.F., Capasso F.
15:00 00317 Microencapsulation of Paraffins and Fatty Acids for Thermal Energy Storage *Paksoy H.O., $Konuklu Y., Mazman M.
15:40 End of Session

IN6Room 206 A

Main Group Chemistry

Organizer(s) - Andrew McWilliams
Chair(s) - A. McWilliams

13:40 00318 Strong C-centered Bases: From Highly Anionic Coordination Complexes of Organometallic Reagents to Novel Reactions of N-Heterocyclic Carbenes Clyburne J.A.C.
14:20 00319 Click-type Reactions Using Strained Phosphorus Heterocycles Streubel R.
15:00 00320 Synthesis and Structural Characterization of 1,2,4,6-selenatriazines and 1,2,4,6-selenatriazinyls *$Boeré R.T., Zhou J., Roemmele T.L.
15:20 00321 Heterocyclic Bis-1,2,3-dithiazoles with Zwitterionic Ground States and Related Radicals Mailman A., Winter S.M., Roberts R.J., Cvrkalj K., Yu X., *Oakley R.T.
15:40 Coffee Break
16:00 00322 Zinc Chalcogenolate Complexes as Molecular Precursors to Manganese (II) Containing Ternary Nanoclusters $Khadka C.B., *Corrigan J.F.
16:20 00323 Formation and Oxidation of Trichalcogeno PCP-Bridged Ligands Konu J., *Chivers T.
16:40 00324 A Radical Approach to Main Group Materials Oakley R.T.
17:20 00325 The Addition of Amides to Group 14 (Di)metallenes Hardwick J.A., $Baines K.M.
17:40 00326 The Oxide Fluoride Chemistry of Xenon(IV) Brock D.S., $Mercier H.P. A., Schrobilgen G.J.
18:00 End of Session

IN8Room 206 C

N-heterocyclic Carbene Chemistry

Organizer(s) - Dmitri Goussev
Chair(s) - M.C. Organ

13:40 00327 Platinum Group Metal Complexes Bearing a Primary Amino-functionalized N-Heterocyclic Carbene as Ligand-metal Bifunctional Catalysts in the Hydrogenation of Ketones O W. W. N., Lough A.J., $Morris R.H.
14:00 00328 Unexpected Reactivity of a Phosphaalkene with an N-Heterocyclic Carbene *$Gates D.P., Bates J.I., Kennepohl P.
14:20 00329 Thermally Robust Ruthenium Phosphonium Alkylidene Catalysts *Leitao E.M., $Piers W. E.
14:40 00330 A Two-Step Synthesis of Chiral Pyrroloimidazol(in)ylidene Precatalysts: Implications for Catalyst Development John J., Xu S., Akong R., *Metallinos C.
15:00 00331 The NHC Off-Switch on Grubbs' Metathesis Catalysts Diver S.T., Keister J.B.
15:40 Coffee Break
16:00 00332 Expanding the Limits: Tuning the Electronic Properties of N-Heterocyclic Carbenes Hobbs M.G., Krahulic K.E., Welsh P., Knapp C.J., Forster T.D., Tuononen H.M., Ziegler T., *$Roesler R.
16:40 00333 NHC and Related N-Heterocyclic Systems: Building Blocks for Multidentate Ligands and New Modified Ring Structures *Ganter C., Willms H., Hildebrandt B., Braun M.
17:00 00334 Chiral Non-Symmetric NHC-Carbene Complexes with Dioxolane Backbone. Heterogenization on Structured Mesoporous Materials and Catalytic Applications Hernández M., *Sánchez F., Villaverde G., Corma A.
17:20 00335 Reactivity of A Golden Synthon *$Nolan S.P., Ramon R.S., Gaillard S, Slawin A.M.Z., Nun P., Boogaerts I.
18:00 End of Session

IN10Room 205 A

Seminar in Honour of Dick Puddephatt

Organizer(s) - Datong Song
Chair(s) - D. Fogg

13:40 00336 Carbon-Hydrogen or Silicon-Carbon Bond Activation by Organoplatinum Complexes *$Puddephatt R.J., Safa M.
14:00 00337 The Hidden Face of the Pd3(dppm)3(CO)n Clusters (n = +2, +1, 0, -1, -2) *$Harvey P.D., Mugnier Y., Lucas D., Boeré R., Jugé S.
14:20 00338 Recent Adventures in Photoluminescent d10 Complexes *$Eisenberg R., Manbeck G.F., Brennessel W., Evans C.
15:00 00339 Adventures with Platinum-based Metallacycles: Syntheses, Luminescence Properties, and Oxidative Addition Reactions Involving 9,10-Dihydroplatinaanthracenes *$Fekl U., De Crisci A.G.
15:20 00340 Oligonuclear Complexes for the Photochemical Production of Hydrogen *$Hanan G.S., Cooke M. W., Hirahara M., Sakai K.
15:40 Coffee Break
16:00 00341 Recent Advances in Homogeneous Oxidation of Hydrocarbons with Platinum and Palladium Complexes *$Bercaw J.E., Labinger J.A.
16:40 00342 Activation of a C-H bond of Trimethylphosphine to Form a Dimeric P, C-Bridged Bimetallic Palladium Complex *$Cavell R.G., Ma G.-B., McDonald R.
17:00 00343 The Reactivity of the Complex [PtMe2(1,2-di-2-pyridylethane)] Safa M.S., *Jennings M.C., $Puddephatt R.J
17:20 00344 Reactions of Late Transition Metal Complexes with Molecular Oxygen Goldberg K.I.
18:00 End of Session

IN11Room 205 B D

Synthesis and Applications of Boron Compounds (joint with OR12)

Organizer(s) - Robert Batey; Cathleen Crudden

13:40 See OR12

18:00 End of Session

MS5Room 202 D

Force Spectroscopy on Macromolecules: From Single Molecules to Materials (joint with PT4)

Organizer(s) - Hongbin Li
Chair(s) - H. Li; G. Walker

13:40 00345 Synthesis and Single Molecule Force Studies of Biomimetic Modular Polymers *$Guan Z.
14:20 00346 Force Spectroscopy on Macromolecules at Hydrophobic Interfaces *$Walker G.C., Li I.T.S., Shi W.
15:00 00347 Using Optical Forces to Probe Mechanical Response from Single Proteins to Biomaterials Downing B.P.B., van der Horst A., Farré A., *$Forde N.R.
15:40 Coffee Break
16:00 00348 New Approaches in Force Spectroscopy: From Enzyme Kinetics to Single-Molecule Centrifugation *$Wong W.P.
16:40 00349 Mechanical Engineering of Proteins: From Single Molecules to Biomaterials *$Li H., Lv S., Cao Y.
17:20 00350 Cholesterol-Dependent Nanomechanical Stability of Phase-Segregated Multicomponent Lipid Bilayers Sullan R.M.A, Li J.K., Hao C.C., Walker G.C., *Zou S.
17:40 00351 Comparative Mechanical Investigations on type I Collagen Aggregates via Nanoindentation Cheng C.C.H., *$Goh M.C.
18:00 End of Session

MS6Room 202 A

Green Polymer Production and Processing

Organizer(s) - Shiping Zhu; Michael Cunningham
Chair(s) - M. Cunningham

13:40 00352 New Biobased Materials through Blends, Nanoblends and Hierarchical Nano-Biocomposites: Present and Future Mohnaty A.
14:20 00353 Solvent-free Preparation of Isobutylene-rich Ionomeric Elastomers Malberg S., *Whitney R.A., $Parent J.S.
14:40 00354 CO2-Triggered Redispersable Polymer Colloids Mihara M., *Jessop P.G., $Cunningham M.
15:00 00355 Ring-Opening Polymerization of Lactones in a Packed-Bed Enzymatic Reactor *Wosnick J.H., Faucher S., Pereira L.
15:40 Coffee Break
16:00 Chul Park

16:30 00356 Green Plasticizer Development *Maric M., $Cooper D.G., Leask R.L., Yargeau V., Nicell J.A., Kermanshahi pour A., Firlotte N., Erythropel H., Shi G.
17:00 00357 Process and Product Development for Controlled-Radical Polymerization Systems: Towards a Sustainable Commercial Technology *$Hutchinson R.A.
17:30 00358 Surface Modification of Wood Fiber and their Utilization in In-situ Polymerization to Achieve Wood Fiber-Polypropylene Composite Reddy C.R., *Simon L.
18:00 End of Session

MS8Room 206 F

Recent Advances in Organic Electronics

Organizer(s) - Thomas Baumgartner; Warren Piers; Rik Tykwinski
Chair(s) - W. Piers; L. Mercier

13:40 Joint with MT6 and OR10. See MT6.

18:00 End of Session

MT3Room 201 E

Inorganic Nanostructured Materials

Organizer(s) - Buriak; Harris
Chair(s) - Buriak; Harris

13:40 00359 Hybrid Nano-Inorganic Cages Macdonald J.E., Popov I., Banin U.
14:20 00360 Writing on Superhydrophobic Post Array Surfaces for the Directed Deposition of 3D Nanostructures *Hatton B.D., $Aizenberg J.
14:40 00361 Synthesis and Plasmonic Properties of Monodisperse Silver Nanoparticles: Decahedra, Pentagonal Rods, Cubes, Bipyramids, etc. *Kitaev V., Cathcart N., McEachran M., Pietrobon B., Frank A.J.
15:00 00362 Gold Removal from the Tips of Silicon Nanorods Hessel C.M., Heitsch A.T., $Korgel B.A.
15:40 Coffee Break
16:00 00363 Rational Design of Bimetallic Nanoparticle Catalysts on Oxide Supports Dash P., Calver C.F., *$Scott R. W. J.
16:20 00364 Selective Grafting Functionality onto Mesoporous Silicas Webb J.D., $Crudden C.M.
16:40 00365 Screening of Bimetallic Heterogeneous Nanoparticle Catalysts for Arene Hydrogenation Activity under Ambient Conditions Dehm N.A., Zhang X., $Buriak J.M.
17:00 End of Session

MT6Room 206 F

Recent Advances in Organic Electronics (joint with OR10)

Organizer(s) - Thomas Baumgartner; Warren Piers; Rik Tykwinski
Chair(s) - W. Piers; L. Mercier

13:40 00366 Material Design for Organic Electronics *$Anthony J.E.
14:20 00367 1,8-Pyrenylene-Ethynylene Macrocycles *$Bodwell G.J., Gandikota V.R.
14:40 00368 From Molecules to Materials *$Nuckolls C.
15:20 00369 Boron Containing Polycyclic Aromatic Hydrocarbons Mercier L.G., $Piers W. E.
15:40 Coffee Break
16:00 00370 Boronsubphthalocyanine Materials for Organic Electronics: Dyes, Sublimates and Engineered Crystals *$Bender T.P., Morse G.E., Paton A., Brisson E.
16:20 00371 Diazaphosphole- and Thiadiazole Oxides as Potential Building Blocks for Organic Electronics Linder T., *Baumgartner T., $Sutherland T.C.
16:40 00372 Intramolecular Double Cyclizations for New p-Conjugated Skeletons *$Yamaguchi S.
17:20 00373 Conjugated Azomethines Dufresne S., *$Skene W. G.
17:40 00374 Mesomorphism and Electronic Properties of Discotic Triphenylene and Phthalocyanine Derivatives Ahmida M.M., Mahoney S., Kayal H., *Eichhorn S.H., Donnio B., Guillon D., Shimizu Y.
18:00 End of Session

OR1Room 205 C

Cancer Therapeutics (joint with BM4)

Organizer(s) - Louise Edwards; David Uehling; Methvin Issac
Chair(s) - L. Edwards

13:40 See BM4

18:00 End of Session

OR4Room 202 C


Organizer(s) - Mark S. Taylor
Chair(s) - A. Boyer

13:40 00375 Towards Efficient Peptide Macrocyclization with Distorted Aziridine-Amide Bonds White C.J., $Yudin A.K.
14:00 00376 Formation of Carbocycles by Intramolecular Conjugate Displacement: Scope and Mechanistic Insights Wang L., Prabhudas B., *Clive D.L.J.
14:20 00377 Synthesis of Amino Acid Precursors and c,d-unsaturated Carbonyls via a Copper Coupling - Claisen Rearrangement Sequence *$Daoust B., Rahem N.
14:40 00378 Domino Direct-Arylation/N-Arylation: A General Strategy for the Synthesis of Heterocycles Candito D.A., Larnaud F., Sumida Y., Blanchot M., *$Lautens M.
15:00 00379 Stereoselective Synthesis of 3-Aryloctahydroindoles and Application in a Formal Synthesis of (-)-Pancracine Lingampally R., *$Pansare S.V.
15:20 00380 The Vinylogous Aza-Morita-Baylis-Hillman Reaction of Activated 1,3-Butadienes Clary K.N., $Back T.G.
15:40 Coffee Break
16:00 00381 CaSH (Camphor Sulfonyl Hydrazine) and CSI (Chiral Sulfonimide) Organocatalysis *$Lee A. W. M., Chen L.Y., He H., Lee Q.H.
16:20 00382 Rhodium-Catalyzed Hydroarylation of Strained Alkenes: Application Towards a Domino Synthesis of Benzofuranones Panteleev J., Menard F., *$Lautens M.
16:40 00383 The Synthesis of Chiral b-amino Sulfoxides from Sulfenate Anions *Soderman S.C., $Schwan A.L.
17:00 00384 Cu-catalyzed Monoarylation of a Semicarbazone Building Block for the Parallel Synthesis of Aryl-Aza Glycine Containing Aza-peptides Proulx C., $Lubell W.D.
17:20 00385 Rhodium Catalyzed Enantioselective Desymmetrization of meso-Alkenes Newman S.G., $Lautens M.
17:40 00386 Anti-Markovnikov Selective Wacker Oxidations of Phthalimide Protected Allylic Amines: a New Catalytic Route to b3-Amino Acids Weiner B., Baeza A., Jerphagnon T., *Feringa B.L.
18:00 End of Session

OR6Room 206 B D

Modern Physical Organic Chemistry

Organizer(s) - Fraser Hof
Chair(s) - E. Gillies; G. Cosa

13:40 00387 A Physical Organic Approach to Bioinspired Nanoscale Adhesive Agents *$Zimmerman S.C.
14:20 00388 Chiral Recognition for the Complexation Dynamics of b-Cyclodextrin (b-CD) with a Chiral Guest Tang H., Dyck A., Olague L., Li Y., Holzwarth J., *Bohne C.
14:40 00389 Binding Studies on Pi-stacked Arginine Motifs Wang X., *$Hof F.
15:00 00390 [6-deoxy-6-(2-aminoethylsulfanyl)]-b-cyclodextrin As a Versatile Scaffold for Sensor Design *$Nitz M., Gomez R., Cao P., Malyshev D.
15:40 Coffee Break
16:00 00391 Structured Peptides, Molecular Structure, and Biological Function Waters M.L.
16:40 00392 Internal Return of Carbon Dioxide in Decarboxylation: Catalysis of Separation and Altered Carbon Kinetic Isotope Effects Mundle S.O.C., *$Kluger R., Sherwood Lollar B., Lacrampe-Couloume G.
17:00 00393 Monitoring Free-Radical Mediated Oxidation of Tocopherol-like Antioxidants in Model Lipid Membranes: Ensemble and Single Molecule Fluorescence Studies Godin R., Liu H.-W., Krumova K., *$Cosa G.
17:20 00394 A Solvent having Switchable Hydrophilicity Carrier A.J., Phan L., Robinson S., Dürr C.J., Harjani J.R., Kozycz L.M., *$Jessop P.G.
17:40 00395 The Dogma that Nitroxides Do Not React with Oxygen-Centered Radicals Is No More *$Pratt D.A., Amorati R., Pedulli G.F., Valgimigli L.
18:00 End of Session

OR10Room 206 F

Recent Advances in Organic Electronics (joint with MT6)

Organizer(s) - Thomas Baumgartner; Warren Piers; Rik Tykwinski
Chair(s) - W. Piers; L. Mercier

13:40 See MT6.

18:00 End of Session

OR12Room 205 B D

Synthesis and Applications of Boron Compounds (joint with IN11)

Organizer(s) - Robert Batey; Cathleen Crudden

13:40 00396 Bonding Boron to Aromatic Metalation Synthetic Strategies Snieckus V.
14:40 00397 Substituent Effects Determine the Solvolytic Stability of Aryltrifluoroborates *$Perrin D.M., Ting R., Li Y., Harwig C., Lo J.
15:00 00398 Boron Reagents in Process Chemistry: Excellent Reagents for Stereoselective Synthesis Matos K., *Burkhardt E.
15:40 Coffee Break
16:00 00399 Chemoselective, pH-Neutral, Desulfitative Coupling Reactions of Boronic Acids with Thioorganics. Discovery, Scope and Limitations, and Mechanism Liebeskind L.S.
16:40 00400 Synthetic Applications of Potassium Organotrifluoroborates - Towards the Total Synthesis of (+)-Antimycin A1b and Unnatural Analogues Janetzko J., *$Batey R.A.
17:00 00401 Catalytic CH Borylation: Synergy Between Experiment and Theory Vanchura II,B.A., Preshlock S.M., Roosen P.C., Chotana A.G., Christian C.F., Singleton D.A., Maleczka Jr.,R.E., *$Smith III,M.R.
17:40 00402 Transition Metal-Free Synthesis of Anilines from Boronic Acids *$McCubbin J.A., Voth S.
18:00 End of Session

PT1Room 203 D


Organizer(s) - G. Walker
Chair(s) - G. Walker

13:40 00403 Bioplasmonic Sensors Based on Gold Nanostructures *$Brolo A.G.
14:20 00404 The Role of Geometry, Period, and Array Symmetry on the Extraordinary Optical Transmission of Composite Nanoparticle Nanoaperture Arrays *$Waldeck D.H.
15:00 00405 Surface Enhanced Raman Spectroscopy: Connecting Theory and Experiment *$Schatz G.C.
15:40 Coffee Break
16:00 00406 Nanohole, Microhole and Nanodot Arrays as Raman and SPR (Bio)Chemical Sensors *Masson J.F., Live L.S., Murray-Méthot M.P.
16:40 00407 Tailored Plasmonic Nanostructures for Enhanced Sensing and Spectroscopy *$Gordon R., Brolo A.G., Sinton D., Kavanagh K.L.
17:20 00408 Lipid Bilayer Functionalized Aperture Arrays in Au Surfaces for Sensing Applications Ip S., Kofke M., Waldeck D.H., *$Walker G.C., Li J.
17:40 00409 Designing and Tuning Fisher's Pattern for Raman Studies of Organized Bioassemblies *$Lagugné-Labarthet F., Galarreta B.C.
18:00 End of Session

PT2Room 201 D

Coherence and Decoherence in Molecular Dynamics

Organizer(s) - Paul Brumer
Chair(s) - P. Brumer

13:40 00410 Spatial Separation of Enantiomers by Coherent Optical Means Shapiro M., *Li X., $Shapiro M.
14:20 00411 Molecular Vibrational Cooling Through Optical Pumping Using Shaped Laser *$Pillet P.
15:00 00412 Tuning Two-body and Many-body Dynamics of Ultracold Molecules with Laser Fields *$Krems R.V., Herrera F., Alyabyshev S., Li Z., Litinskaya M.
15:40 Coffee Break
16:00 00413 Decoherence in Nanoscale Materials Prezhdo O.V.
16:40 00414 Mechanistic Coherent Control Experiments Brixner T.
17:20 00415 Indistinguishability and Interference in the Coherent Control of Atomic and Molecular Processes Gong J., Brumer P.
18:00 End of Session

PT3Room 201 C

Electrochemistry and Electrocatalysis

Organizer(s) - Gregory Jerkiewicz; Michael Eikerling

13:40 See AN4

18:00 End of Session

PT4Room 202 D

Force Spectroscopy on Macromolecules: From Single Molecules to Materials (joint with MS5)

Organizer(s) - Hongbin Li
Chair(s) - H. Li; G. Walker

13:40 See MS5

18:00 End of Session

PT7Room 201 A

Solid State NMR: Methods and Applications

Organizer(s) - David Bryce; Gillian Goward
Chair(s) - D. Bryce

13:40 00416 Developing NMR Tools to Study Nanoliter Solids and Liquids Samples Kentgens A.
14:20 00417 High-Resolution NMR of Nanolitre-sized Solid and Semi-solid Samples with Magic Angle Coil Spinning (MACS) *Aguiar P.M., Wong A., Bonhomme C., Babonneau F., $Sakellariou D.
14:40 00418 Multinuclear Solid-State NMR Studies of Microencapsulated Scandium Catalysts Rossini A.J., Hildebrand M.P., *$Schurko R.W., Hazendonk P.W.
15:00 00419 Recent Progress in Dipolar Recoupling of Quadrupolar Nuclei and High-Resolution Proton Solid-State NMR *$Brinkmann A., Moudrakovski I., Vasa S.K., Janssen H., Grimminck D.L.A., Meerts W.L., Kentgens A.P.M., Edén M.
15:20 00420 Solid-State NMR Study of the Mechanism of Action of Novel Amphipathic Cationic Peptides in Model Membranes *$Auger M., Noël M., Lorin A., Manai R., Valois-Paillard G., Provencher M.-E., Voyer N.
15:40 Coffee Break
16:00 00421 NMR Spectroscopy and Polymorphism Ripmeester J., Terskikh V., Moudrakovski I., Brinkmann A., Enright G., Lang S., Ratcliffe C.
16:40 00422 High-Resolution 13C NMR Spectroscopy in Non-perfluorinated Systems *$Hazendonk P., Borisov A., Montina T., Wormald P.
17:00 00423 Structure of Acidic Guanosine 5'-Monophosphate G-Quadruplexes Confirmed 50 Years Later Using Solid-State NMR Experiments Kwan I.C.M., $Wu G.
17:20 00424 New Advances in Ultra-Wideline Solid-State NMR Spectroscopy *$Schurko R.W., Hamaed H., Harris K.J., Lucier B.E.G., MacGregor A.W., O'Dell L.A., Rossini A.J.
17:40 End of Session

SS1Room 201 C

Electrochemistry and Electrocatalysis (joint with AN4)

Organizer(s) - Gregory Jerkiewicz; Michael Eikerling

13:40 See AN4

18:00 End of Session

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Bold text denotes the presenting author.   If present, * denotes the corresponding author and $ denotes the principal investigator.

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