93rd Canadian Chemistry Conference and Exhibition


Organic Chemistry

Sunday AM

OR4Room 202 C

General

Organizer(s) - Mark S. Taylor
Chair(s) - A. Boyer

08:00 00144 An Indirect Approach Toward Benzo-fused Carbocycles and Cascade Intramolecular Conjugate Displacement Reactions Chen Z., Sunasee R., *$Clive D.L.J.
08:20 00145 Enantioselective Total Synthesis of (1R, 1'S)-temuconine, a Bisbenzytetrahydroisoquinoline Alkaloid Zein A.L., *Georghiou P.E.
08:40 00146 Photochemical Rearrangement of N-substituted lactams: A New Route to N-heterocycles through Concerted Ring Contraction Winter D.K., Drouin A., Lessard J., Spino C.
09:00 00147 THAM-based Derivatives as Entries to Novel Antibacterial Pharmacophores Calzavara J., $McNulty J., *Wright G.
09:20 00148 Progress Towards Intermolecular Desulfinylative and Decarboxylative Palladium-Catalyzed Cross-Coupling Reactions Bilodeau F., *Forgione P., Brochu M.-C., Thesen K.H., Guimond N., Desharnais B., Sévigny S., Aly S.
09:40 00149 Organocatalytic Tether Formation: A Strategy Enabling Directed Intermolecular Cope-Type Hydroaminations Ng P.J., MacDonald M.J., $Beauchemin A.M.
10:00 End of Session

OR6Room 206 B D

Modern Physical Organic Chemistry

Organizer(s) - Fraser Hof
Chair(s) - S. Murphy

08:00 00150 Constitutional Exchange in CN containing Molecules *$Petitjean A., Keyes L., Barker S.
08:20 00151 A Theoretical Study of the Copper (II) Carboxylate-promoted Aminooxygenation of Unactivated Olefins *Dudding T., Belding L., Paderes M., $Chemler S.
08:40 00152 Evidence for C-H...O Interactions from Aromatic ortho-H Atoms in NSO Compounds Boateng S., Malla P., Li S., *$Muchall H.M.
09:00 00153 Halogen-bonding in Organic Solution: Fundamental Studies and New Applications Sarwar M.G., Dragisic B., Salsberg L.J., Chudzinski M.G., Gouliaras C., *$Taylor M.S.
09:20 00154 Anions and Aromatic Rings: Fluorescent Signaling and Attractive Interactions? *$Johnson D.W.
10:00 End of Session


Sunday PM

OR1Room 205 C

Cancer Therapeutics (joint with BM4)

Organizer(s) - Louise Edwards; David Uehling; Methvin Issac
Chair(s) - L. Edwards

13:40 See BM4

18:00 End of Session

OR4Room 202 C

General

Organizer(s) - Mark S. Taylor
Chair(s) - A. Boyer

13:40 00375 Towards Efficient Peptide Macrocyclization with Distorted Aziridine-Amide Bonds White C.J., $Yudin A.K.
14:00 00376 Formation of Carbocycles by Intramolecular Conjugate Displacement: Scope and Mechanistic Insights Wang L., Prabhudas B., *Clive D.L.J.
14:20 00377 Synthesis of Amino Acid Precursors and c,d-unsaturated Carbonyls via a Copper Coupling - Claisen Rearrangement Sequence *$Daoust B., Rahem N.
14:40 00378 Domino Direct-Arylation/N-Arylation: A General Strategy for the Synthesis of Heterocycles Candito D.A., Larnaud F., Sumida Y., Blanchot M., *$Lautens M.
15:00 00379 Stereoselective Synthesis of 3-Aryloctahydroindoles and Application in a Formal Synthesis of (-)-Pancracine Lingampally R., *$Pansare S.V.
15:20 00380 The Vinylogous Aza-Morita-Baylis-Hillman Reaction of Activated 1,3-Butadienes Clary K.N., $Back T.G.
15:40 Coffee Break
16:00 00381 CaSH (Camphor Sulfonyl Hydrazine) and CSI (Chiral Sulfonimide) Organocatalysis *$Lee A. W. M., Chen L.Y., He H., Lee Q.H.
16:20 00382 Rhodium-Catalyzed Hydroarylation of Strained Alkenes: Application Towards a Domino Synthesis of Benzofuranones Panteleev J., Menard F., *$Lautens M.
16:40 00383 The Synthesis of Chiral b-amino Sulfoxides from Sulfenate Anions *Soderman S.C., $Schwan A.L.
17:00 00384 Cu-catalyzed Monoarylation of a Semicarbazone Building Block for the Parallel Synthesis of Aryl-Aza Glycine Containing Aza-peptides Proulx C., $Lubell W.D.
17:20 00385 Rhodium Catalyzed Enantioselective Desymmetrization of meso-Alkenes Newman S.G., $Lautens M.
17:40 00386 Anti-Markovnikov Selective Wacker Oxidations of Phthalimide Protected Allylic Amines: a New Catalytic Route to b3-Amino Acids Weiner B., Baeza A., Jerphagnon T., *Feringa B.L.
18:00 End of Session

OR6Room 206 B D

Modern Physical Organic Chemistry

Organizer(s) - Fraser Hof
Chair(s) - E. Gillies; G. Cosa

13:40 00387 A Physical Organic Approach to Bioinspired Nanoscale Adhesive Agents *$Zimmerman S.C.
14:20 00388 Chiral Recognition for the Complexation Dynamics of b-Cyclodextrin (b-CD) with a Chiral Guest Tang H., Dyck A., Olague L., Li Y., Holzwarth J., *Bohne C.
14:40 00389 Binding Studies on Pi-stacked Arginine Motifs Wang X., *$Hof F.
15:00 00390 [6-deoxy-6-(2-aminoethylsulfanyl)]-b-cyclodextrin As a Versatile Scaffold for Sensor Design *$Nitz M., Gomez R., Cao P., Malyshev D.
15:40 Coffee Break
16:00 00391 Structured Peptides, Molecular Structure, and Biological Function Waters M.L.
16:40 00392 Internal Return of Carbon Dioxide in Decarboxylation: Catalysis of Separation and Altered Carbon Kinetic Isotope Effects Mundle S.O.C., *$Kluger R., Sherwood Lollar B., Lacrampe-Couloume G.
17:00 00393 Monitoring Free-Radical Mediated Oxidation of Tocopherol-like Antioxidants in Model Lipid Membranes: Ensemble and Single Molecule Fluorescence Studies Godin R., Liu H.-W., Krumova K., *$Cosa G.
17:20 00394 A Solvent having Switchable Hydrophilicity Carrier A.J., Phan L., Robinson S., Dürr C.J., Harjani J.R., Kozycz L.M., *$Jessop P.G.
17:40 00395 The Dogma that Nitroxides Do Not React with Oxygen-Centered Radicals Is No More *$Pratt D.A., Amorati R., Pedulli G.F., Valgimigli L.
18:00 End of Session

OR10Room 206 F

Recent Advances in Organic Electronics (joint with MT6)

Organizer(s) - Thomas Baumgartner; Warren Piers; Rik Tykwinski
Chair(s) - W. Piers; L. Mercier

13:40 See MT6.

18:00 End of Session

OR12Room 205 B D

Synthesis and Applications of Boron Compounds (joint with IN11)

Organizer(s) - Robert Batey; Cathleen Crudden

13:40 00396 Bonding Boron to Aromatic Metalation Synthetic Strategies Snieckus V.
14:40 00397 Substituent Effects Determine the Solvolytic Stability of Aryltrifluoroborates *$Perrin D.M., Ting R., Li Y., Harwig C., Lo J.
15:00 00398 Boron Reagents in Process Chemistry: Excellent Reagents for Stereoselective Synthesis Matos K., *Burkhardt E.
15:40 Coffee Break
16:00 00399 Chemoselective, pH-Neutral, Desulfitative Coupling Reactions of Boronic Acids with Thioorganics. Discovery, Scope and Limitations, and Mechanism Liebeskind L.S.
16:40 00400 Synthetic Applications of Potassium Organotrifluoroborates - Towards the Total Synthesis of (+)-Antimycin A1b and Unnatural Analogues Janetzko J., *$Batey R.A.
17:00 00401 Catalytic CH Borylation: Synergy Between Experiment and Theory Vanchura II,B.A., Preshlock S.M., Roosen P.C., Chotana A.G., Christian C.F., Singleton D.A., Maleczka Jr.,R.E., *$Smith III,M.R.
17:40 00402 Transition Metal-Free Synthesis of Anilines from Boronic Acids *$McCubbin J.A., Voth S.
18:00 End of Session


Monday AM

OR1Room 205 C

Cancer Therapeutics (joint with BM4)

Organizer(s) - Louise Edwards; David Uehling; Methvin Issac
Chair(s) - L. Edwards

08:00 See BM4

12:20 End of Session

OR6Room 206 B D

Modern Physical Organic Chemistry

Organizer(s) - Fraser Hof
Chair(s) - S. Eisler

08:00 00614 Mechanistic Study of the Formation of Silene/Silylene Intermediates in a Catalytic Chemical Vapor Deposition Process *$Shi Y.J., Tong L.
08:20 00615 Study of Steric and Electronic Effects on the Reactivities of Transient Diarylsilylenes by Laser Flash Photolysis Methods Bhattacharya A., *$Leigh W.J.
08:40 00616 Supramolecular Assistance in Catalysis *$Schmitzer A.R., Gauchot V., Lacour M., Leclercq L.
09:00 00617 Explosives Detection with 9,10-Dihydroacridine Derivatives Andrew T.L., *$Swager T.M.
09:20 00618 'Remote-Control' Photo-Release of 'Caged' Compounds Using Near Infrared Light and Upconverting Nanoparticles $Carling C.-J., Nourmohammodian F., Boyer J.-C., *Branda N.R.
09:40 00619 A Glimpse into the Labs at the Xerox Research Centre of Canada Chretien M.N., Heuft M.A.
10:00 End of Session

OR10Room 206 F

Recent Advances in Organic Electronics (joint with MT6)

Organizer(s) - Thomas Baumgartner; Warren Piers; Rik Tykwinski
Chair(s) - R. Tykwinski

08:20 See MT6.

12:20 End of Session

OR11Room 206 B D

Recent Developments in Heterocyclic Chemistry

Organizer(s) - Andre M. Beauchemin
Chair(s) - M. Gravel

10:20 00620 "Aromatic Ring Umpolung", a Rapid Access to the Main Core of Several Heterocyclic Natural Products Canesi S.
11:00 00621 Rhodium(III) Catalyzed Intermolecular Hydro(hetero)arylation of Alkynes *Schipper D.J., Hutchinson M., $Fagnou K.
11:20 00622 Iridium-catalyzed Intramolecular Hydroamination of Aminoalkenes: Scope and Mechanism Hesp K.D., $Stradiotto M.
11:40 00623 Redox Neutral Reaction Cascades *$Seidel D.
12:20 End of Session

OR12Room 205 B D

Synthesis and Applications of Boron Compounds (joint with IN11)

Organizer(s) - Robert Batey; Cathleen Crudden

08:00 00624 Synthesis and Reactivity of Chiral "Frustrated Lewis Pair" Complexes Heiden Z.M., *$Stephan D. W.
08:20 00625 Boron Chelate Complexes of Indigo Derivatives *$Nawn G., Hicks R.G.
08:40 00626 A Diversity of Metal-Ligand Interactions in Halide (X = I, Br, Cl, F) and Halide-Free Ambiphilic Ligand Rhodium Complexes Cowie B.E., *Emslie D.J.H.
09:00 00627 Synthesis, Characterization, and Chemical Bonding of Metal Amidoborane Complexes *Wolstenholme D.J., McGrady G.S.
09:20 00628 Mechanistic Studies of Catalyzed Amine-Borane Dehydrogenation Baker R.T.
10:00 Coffee Break
10:20 00629 Chemical Synthesis of Sidewall Segments of Carbon Nanotubes: Cycloparaphenylenes and Related Carbon Nanorings *$Itami K.
11:00 00630 Transition Metal Complex-Catalyzed Dehydrogenation of Amine-Boranes in Ionic Liquids $Wright W.R.H., *Baker R.T., Sneddon L.G.
11:20 00631 Photochromic Organoboron Compounds *$Wang S., Baik C., Amarne H., Murphy S., Hudson Z.M.
12:00 00632 Borohydrides from Hantzsch's Esters Webb J.D., *Laberge V.S., $Crudden C.M.
12:20 End of Session

ORPConstitution Hall

Posters

Organizer(s) - Mark S. Taylor
Chair(s) - M. Taylor

From 12:20 until 13:40

Poster sessions are from 12:20 - 13:40 and 17:40 - 19:20.

12:20 00633 Novel Organosilicas - Design, Synthesis and Catalysis MacQuarrie S.M., Cross E., Fraser C., Larade M., MacLean C., Sponagle B, Tait M.
12:20 00634 Synthesis of Novel Cyclodextrin Derivatives for Liquid Crystal Studies Ward S, $Ling C.C.
12:20 00635 Electrochemical Oxidations of Cyclic and Acyclic Thioureas *$Khare R., Ralhan N.K.
12:20 00636 Photoisomerization of Bis-azobenzene and its Effects on Structural Changes of Peptides and Proteins $Samanta S., Woolley G.A.ndrew
12:20 00637 Recognition of Anions and Neutral Guests by Dicationic Pyridine-2,6-dicarboxamide Receptors Dorazco-González A., *Höpfl H., Medrano F., $Yatsimirsky A.
12:20 00638 Probing the Structure and Stability of the Covalently Bound HCN and HNC Dimers Using Neutralization-Reionization Mass Spectrometry and Computations Jobst K.J., *Terlouw J.K.
12:20 00639 Photochemcial Synthesis of Aryl Trifluorophthalonitriles and their Phthalocyanine Derivatives *$Nolan K., Murphy B., Oelgemoeller M.
12:20 00640 Electrochemical Oxidations of Cyclic and Acyclic Thioureas *$Khare R., Ralhan N.K.
12:20 00641 Late Stage Modification of Cyclic Peptides Rai V., Hili R., *$Yudin A.K.
12:20 00642 A Strategy for the Synthesis of [n]Phenacenes ­ Potential Precursors to Voegtle Aromatic Belts Gandikota V.R., Unikela K.S., *$Bodwell G.J.
12:20 00643 Mixed Glycoluril/Crown Ether Cage: Synthesis and Properties of Self-assembly at Water/Air Interface Vidal M., Kairouz K., *Schmitzer A.
12:20 00644 Development of Catalytic Enantioselective Intramolecular Alkylations of Oxazolidinone Imides St. Denis J.D., *$Gleason J.L
12:20 00645 Testing the Functional Tolerance of the Piers-Rubinsztajn Reaction: A New Strategy for the Synthesis of Functional Silicones Grande J.B., $Brook M.A.
12:20 00646 Insights into Palladium Catalyzed Difunctionalization with Two Distinct Nucleophiles Webb J.D., Jensen K.H., *Sigman M.S.
12:20 00647 Reactivity of Poleolfins Towards t-Butoxyl Radical: Regioselectivity of Hydrogen Atom Transfer Garrett G.E., *Pratt$ D., $Parent$ J.S.
12:20 00648 Novel Frustrated Lewis Acid/Base Pairs and the Activation of Small Molecules Peuser I., Kehr G., Fröhlich R., *Erker G.
12:20 00649 Boron Based Approach Towards Asymmetric Arylation of Enones Niljianskul N., Turner H., *Chong J.M.
12:20 00650 Synthesis of Thieno[2,3-b]pyridines and Their Derivatives with Potential Bioactivity Ibe J.C., $Lam A., *Mikhaylichenko S.

Graduate Student Posters - General OR

12:20 00651 Iron (III) Amine-bis(phenolate) Complexes as Catalysts for the Alkylation of Aryl Grignard Reagents Qian X., *$Kozak C.M.
12:20 00652 Brassinosteroids: New Synthetic Strategy and Neuroprotective Activity *Ismaili J., $Daoust B., Martinoli M.-G., Longpré F.
12:20 00653 Enzyme-assisted Asymmetrization of Racemic Substituted 1,3-Propanediols Melanson J., Youssef D., Deveau M., Richards J., Huang P.-J.J., Mukherjee C., *$Jha A.
12:20 00654 Synthesis of b-lactones Zepeda-Velázquez C.A., *Khandker J.A., $Harrison P.H.M.
12:20 00655 Mechanistic Investigations of a Dual Catalytic System: The FeCl3/Imidazolidinone Catalyzed Oxyamination of Aldehydes Van Humbeck J.F., Simonovich S.P., *$MacMillan D. W. C.
12:20 00656 Novel Boron-catalyzed Reactivity Lee D., $Taylor M.S.
12:20 00657 Synthesis of (S)-Homocitric Acid Lactone and an Approach to (+)-Lycoperdic Acid Involving Organocatalysis Dyapa R., Adsool S., *$Pansare S.V.
12:20 00658 Ortho-metallated Acetophenone Imine Derivatives as Ligands for Group I, II, XI and XII Metals Beck J.F., *Schmidt J.A.R.
12:20 00659 Asymmetric Conjugate Addition of Alkenylstannanes to Alkylidene Meldrum's Acids Mahoney S.J., Dumas A.M., Lau C.T., *$Fillion E.
12:20 00660 Foldamers Based on Formamidine Motifs Zhao W., Xing L., *$Petitjean A.
12:20 00661 Umbrella-rotaxanes: Towards New Vehicles for Drugs Delivery Chhun C., *Schmitzer A.R.
12:20 00662 Design of Gold Monolayer Cluster Supported Organocatalysts Abeysekera S.D., *$MaGee D.I.
12:20 00663 F-BODIPY Deprotection and Modification Crawford S.M., Thompson A.
12:20 00664 Multicomponent Domino Synthesis of Tetrasubstituted Alkenes through Multiple C-H Functionalization Chai D., Kersten G., Bieler N., *Lautens M.
12:20 00665 Organocatalytic Tether Formation: A Strategy Enabling Directed Intermolecular Amination Reactions MacDonald M.J., Ng P.J., $Beauchemin A.M.
12:20 00666 Synthesis and Clathrates of Unprecedented Oligomeric 7-tert-butyl-2-naphthoide Macrocycles AlHujran T., Dawe L.N., *$Georghiou P.E.
12:20 00667 Preliminary Studies Toward the Development of a General Gold(I)-Catalyzed 6-endo-dig Carbocyclization Barabé F., Bellavance G., Levesque P., $Barriault L.
12:20 00668 Synthesis and Self-Assembling Properties of Amide Functionalized Conjugated Macrocycles *Eisler S., $Bubar A.
12:20 00669 Efficient Catalytic Cleavages of P=S Containing Phosphorothioate Triesters by ortho-Palladated Complexes in Methanol: A Mechanistic Investigation Liu C.T., Maxwell C.I., Neverov A.A., Mosey N.J., Brown R.S.
12:20 00670 Trichloroethylene as a Template for the Modular Construction of Polysubstituted Electron-Rich Alkenes, Dienes, Trienes and Enynes Geary L.M., *Hultin P.G.
12:20 00671 Novel bis-N-sulfinylhydrazines and their Hydrogen-Bonding Patterns Beylis I., *$Muchall H.M.
12:20 00672 Design of a New 1,3-Dipolar Cycloaddition Reagent Morin M.S.T., St-Cyr D., *Arndtsen B.A.
12:20 00673 Palladium Catalyzed Carbonylation of Aryl Iodides. A Simple and Modular Approach to Nitrogen-Containing Heterocycles Quesnel J.S., Bontemps S., *$Arndtsen B.A.
12:20 00674 Intramolecular Cycloadditions and Rearrangements of N-Heterocyclic Carbenes Legault M.C.B., *Moran J., $Pezacki J.P.
12:20 00675 Palladium Catalyzed Multi-component Synthesis of Imidazolines from Imines and Acid Chlorides Xu B., Worrall K., *$Arndtsen B.A.
12:20 00676 Investigating Enantioselectivity and Diastereoselectivity in the Buchwald-Hartwig Reaction Through Desymmetrization of Malonamide Derivatives Matarazzo A., Wylie R.S., *$Viirre R.D.
12:20 00677 The Synthesis of Self Assembled Monolayers Containing Interlocked Molecules Bolla M.A., Carmichael T.B., $Loeb S.J.
12:20 00678 Activation of Cyclopropanes towards Nucleophilic Ring Opening Using Internal Brřnsted Acids Emmett M.R., *Sapeta K.A., $Kerr M.A.
12:20 00679 Postsynthetic Modifications to a Microporous Organic Framework Kerneghan P.A., *Maly K.E.
12:20 00680 Recognition of Halide Anions in Dilute Solution by tridentate Halogen Bond Donor Golam Sarwar M., *$Taylor M.
12:20 00681 Novel Two-Step Synthesis for 2-Aminopyridine and 2-Aminothiophene Synthons Mancuso J., Lin Y.S., Langille A.M., *Tsantrizos Y.S.
12:20 00682 Investigating a Secondary Oxidative Pathway of C-8 Phenolic Deoxyguanosine Adducts $Witham A., *Manderville R.
12:20 00683 Enantioselective Ketone Hydroacylation - Synthesis of Nitrogen-containing Medium-ring Lactones Khan H.A., *$Dong V.M.
12:20 00684 New One Pot Tandem Pericyclic Oxy-Cope/Claisen/Ene/Diels-Alder Sow B., Poulin J., Maclean R., *Barriault L.
12:20 00685 Toward the Control of Three-Dimensional Molecular Structure: Characterization of a Conjugated 1,3,5-Triazine-Based Molecular Switch $Conn G., *Eisler S.
12:20 00686 Application of Chiral Auxiliaries Towards the Total Synthesis of Quebrachamine and Goniomitine Machin B.P., *Bajtos B., $Pagenkopf B.L.
12:20 00687 Exploration of Siloles as Intermediates in Organic Synthesis Stevens A.C., *$Pagenkopf B.L.
12:20 00688 New Strategies for the Palladium-Catalyzed Direct Arylation Allowing Milder Reaction Conditions *René O., Fagnou K.
12:20 00689 Syntheses of Substituted Acetylenic Sulfones *Hossain M.S., $Schwan A.L.
12:20 00690 Competition Kinetics of Oxygen-Centered Radical Cyclizations Leung J.C. T., *Rueda Becerril M., $Sammis G.M.
12:20 00691 Development of Conjugated Copolymers for Carbon Nanotube-Based Solar Cells *Kraft T.M., Aldea G., Buncel E., $Nunzi J.-M.

Synthesis and Applications of Boron Compounds

12:20 00692 Suzuki Cross-Coupling Reactions of Functionalized 1-Phenylpyrazoles Arbaciauskiene E., Holzer W., *Sackus A.
12:20 00693 Broadening the Scope of Cross-Coupling Reactions with Chiral Secondary Boronic Esters $Laberge V.S., Glasspoole B. W., Imao D., *Crudden C.M.
12:20 00694 Boronic Acid-Catalysed Friedel - Crafts Allylation, Benzylation and Propargylation Reactions *$McCubbin J.A., Hosseini H., Nassar C.
12:20 00695 Imine Hydrogenation with Metal-Free Catalysts based on Frustrated Lewis Pairs *Chase P.A., Sargent J.R., Resendes R., $Stephan D.W., Graham T.W., Greenburg S.
12:20 00696 Palladium Catalyzed Suzuki Coupling Of Secondary Boronic Esters With Retention Of Configuration: Mechanistic Studies and the Development of More Active Catalytic Systems Lu Y., *Crudden C.

Recent Developments in Heterocyclic Chemistry

12:20 00697 Unexpected Benzothiopyran Dioxides from Selected Benzyl Alkynyl Sulfones. Evidence for an Allenyl-to-aryl Anion Translocation *$Schwan A.L., Hossain M.S.
12:20 00698 The Carbon-Chlorine Bond as an Activating and Protecting Group in Palladium-Catalyzed Direct Arylation of Heteroaromatics *Liégault B., Petrov I., Gorelsky S.I., $Fagnou K.
12:20 00699 Supported Combinatorial Synthesis of Pyrrolo[3,2-e][1,4]diazepin-2-ones $Boutard N., Duffour-Gallant J., Deaudelin P., *Lubell W.D.
12:20 00700 A Versatile Synthetic Platform Based on Strained Propargyl Amines He Z., *$Yudin A.K.
12:20 00701 Domino Rhodium-catalysed Reactions for the Efficient Synthesis of Polysubstituted Benzofurans and Indoles Boyer A., Isono N., Lackner S., *$Lautens M.
12:20 00702 Verdazyl Cycloadditions and Subsequent Rearrangements: A Synthesis of Oxadiazolones Bancerz M., $Georges M.K.
12:20 00703 Synthesis and Photochromism of Benzo[e]indolo[2,1-b][1,3]benzoxazine Derivatives *Krikstolaityte S., Sackus A., Steponaviciute R., Martynaitis V., Barkauskas M., Vengris M.
12:20 00704 Synthesis of a Tetracyclic Variant of the G-C Motif for the Self-Assembly of Rosette Nanotubes with 1.7 nm Inner Diameter Beingessner R., Borzsonyi G., Yamazaki T., Kovalenko A., *$Fenniri H.
12:20 00705 Synthesis of New Morpholine Derivatives of Phencyclidine with More Analgesic Effects *$Ahmadi A., Khalili M., Naserbakht M., Javadi M.
12:20 00706 1-[1-(2-methylphenyl) (cyclohexyl)]-3-piperidinol as a New Derivative of Phencyclidine; Synthesis and Analgesic Effects on Mice *$Ahmadi A., Solati J., Onagh M., Javadi M.
12:20 00707 Synthesis and Study on Analgesic Effects of New Pyrrole Derivatives of Phencyclidine *$Ahmadi A., Solati J., Pakzad S., Javadi M.

Graduate Student Posters - Recent Developments in Heterocyclic Chemistry

12:20 00708 Synthesis of b-Aminocarbonyls Groups from Aminocarbonylation of Alkenes with Aminoisocyanates $Clavette C., Roveda J.-G., Gorelsky S., *Beauchemin A.M.
12:20 00709 Investigations Involving Pyrrole-Bound Ruthenium Complexes Jackson C.L.M., Al-Shiekh Ali A., *Thompson A.
12:20 00710 Synthesis of 5-Azaindoles via a Cycloaddition Reaction Between Nitriles and Donor-Acceptor Cyclopropanes Moustafa M.M.A., *Pagenkopf B.L.
12:20 00711 Transformations of Unprotected N-H Aziridines Containing a Diazo Group Decker S., $Yudin A.K.

Organic Synthesis: Stereocontrol

12:20 00712 [4+2] Cycloaddition of Donor-Acceptor Cyclobutanes and Aldimines: Stereoselective Synthesis of Piperidine Moustafa M.M.A., *Pagenkopf B.L.
12:20 00713 The First Total Synthesis of Aspergillusol A, an Alpha Glucosidase Inhibitor *$Ullah N., Haladu S.A.
12:20 00714 Lewis-Acid Catalyzed Chemoslelective S-benzylation of Indoline-2-thiones Using Benzyl Alcohols *$Jha M., Enaohwo O.
12:20 00715 Synthesis of p-enriched Phenylalanine Derivatives, and Peptide Coupling of Protected 2-Pyrrolylalanine for the Study of the Influence of Aromatic Density on Prolyl Amide Isomer Population *Dörr A.A., Lubell W.D.
12:20 00716 Regioselective Arylation of Fluorenone Skeleton via Combined Ru- and Pd-Catalyzed Suzuki Cross Coupling Reactions da Silva A.J.M., *$Snieckus V.
12:20 00717 4-Methoxy-2,2'-Bipyrroles: Synthesis, Spectroelectrochemical, and Photophysical Investigation Tshibaka T., Roche I.U., Dufresne S., Lubell W.D., Skene W.G.
12:20 00718 An Investigation Using Methyl Methylenenitronate within the Henry Reaction Pilgrim A., MacDonald F.K., *$Pottie I.R.
12:20 00719 Investigations into the Synthesis of Natural and Unnatural Acyldepsipeptides; A New Class of Antibiotic Drugs Goodreid J.D., *Cossette M., $Batey R.A.
12:20 00720 Synthesis of Substituted Oxazoles by Ritter Reaction of a-Oxo Tosylates Lai P.-S., *Taylor M.S.
12:20 00721 Palladium-Catalyzed Domino Direct Arylation/N-Arylation Blanchot M., Candito D.A., Larnaud F., Sumida Y., *Lautens M.
12:20 00722 Use of Oxidized Piperidine Trimers in Formal [4+2] Cycloadditions Cheung L., $Yudin A.K.
12:20 00723 New Developments on the Oxo-Povarov Reaction Taylor R.R.R., *$Batey R.A.
12:20 00724 Towards the Total Synthesis and Stereochemical Assignment of a Sesquiterpene Isolated from the Coral Clavularia inflata var. luzoniana Bechara W.S., Marcoux D., *Charette A.B.
12:20 00725 N-Alkenyl Aziridines in Organic Synthesis Afagh N., $Yudin A.K.
12:20 00726 Toward the Synthesis of the Diphthamide: A Post-translationally Modified Histidine Amino Acid *Singh S.P., Michaelides A., $Schwan A.L.
12:20 00727 Toward the Synthesis of Aplysamine 6 using Microwave-Assisted Continuous Organic Synthesis (MACOS) Achanta S., Liautard V., Paugh R., *$Organ M.G.
12:20 00728 Total Synthesis of Linoxepin Suhartono M., *$Lautens M.
12:20 00729 Diastereoselective Benzylic Arylation of Tetralins via Friedel-Craft Reactions Liébert C., Brinks M., Davoust M., Hitching J., Krämer K., *Lautens M.
12:20 00730 Synthesis and Initial Evaluation of Pd-PEPPSI-SIPent *$Organ M.G., Mallik D., Tsimerman M.
12:20 00731 Tetrathiafulvalene Vinylogues Based Molecular Tweezers $Chen G., Bouzan S., *Zhao Y.
12:20 00732 Synthesis of an Optically Pure Sulfinate and its Utility in the Asymmetric Synthesis of Chiral Pyrrole-containing Diarylsulfoxides Imam Uddin M., M. Pearce B., *Thompson A.
12:20 00733 Synthesis of Enantioenriched Allenes from 1,1-Cyclopropanediesters $Cérat P., Gritsch P.J., Goudreau S.R., *Charette A.B.
12:20 00734 Selectivity in Reaction Between Benzyl Bromide and Potassium Cyanide in Presence of Alumina and Activated Method *Le Ngoc T., $Le Hoang Tan D.
12:20 00735 Pd-PEPPSI-IPent: Low temperature Negishi Cross-Couplings for the Preparation of Highly Functionalized, Tetra-Ortho-Substituted Biaryls Calimsiz S., Sayah M., *$Organ M.G.
12:20 00736 High Yielding Aminations of Aryl Chlorides Mediated by a Highly-active and Sterically-demanding Pd-NHC Precatalyst: Pd-PEPPSI-iPent *$Organ M.G., Hoi K.H., Calimsiz S.
12:20 00737 Quarternary Salts - Good Synthons in Synthesis of Sym-triazine Derivatives with Wide Spectrum of Biological Activity $Mikhaylichenko S.N., Zaplishnyy V.N.
12:20 00738 Homoallyl as a Nitrogen Protecting Group for the GC Base Diaz J., Beingessner R., Hemraz U.D., Moralez J.G., Azizul H., *$Fenniri H.
12:20 00739 Strategies Towards the Synthesis of GC Base Nucleotides Diaz J., Moralez J.G., Azizul H., *$Fenniri H
12:20 00740 The Use of Silica-bound Reagents in the Preparation of Biologically Useful Compounds *$Priefer R., Grenga P.N., Sumbler B.L., Rudzinski D.M.
12:20 00741 Iron-Catalyzed Coupling of 2-Bromofuran with Grignard Reagents Haner J., *Tam W.
12:20 00742 Synthesis and Biological Evaluation of Selena- and Thiadiazoles Derived from Naturally Occurring Furochromone (Khellin and Visnagin) Atta S.M. Sh., Farrag D.S., El-sayed A.M. K., *Abdel-Rahman A.H.
12:20 00743 Study on Expected Biologically Active Tertiary Amine N-Oxide *$Hanna S.

Graduate Student Posters - Organic Synthesis: Stereocontrol

12:20 00744 A Novel Intramolecular [4+1] Reaction Utilizing Fischer Aminocarbenes for the Synthesis of Bicyclic N-Heterocycles D. Lefebvre L.-P., *Spino C.
12:20 00745 Organocatalytic Aldol Reactions of Dioxanones: Stereocontrolled Approach Towards Hyacinthacine Alkaloids Delawarally K., *Majewski M.
12:20 00746 Regioselectivity in Ruthenium-catalyzed [2+2] Cycloadditions of 2-Aza-3-Oxobicyclo[2.2.1]hept-5-enes with Unsymmetrical Alkynes Durham R., *$Tam W.
12:20 00747 Enantioselective Rhodium(II)-Catalyzed Cyclopropanation of Alkenes with a-EWG Diazoacetophenones: PMP-Ketones as Stereoselectivity Controllers $Lindsay V.N.G., *Charette A.B.
12:20 00748 Intramolecular Nicholas Reaction Approach to Dibenzocyclooctenes Djurdjevic S., *$Green J.R.
12:20 00749 A Traceless Chiral Auxiliary for Asymmetric Aldol Reactions Halperin S.D., *$Britton R.
12:20 00750 Anomalous Heck Reaction of Tertiary Allylic Alcohols under Oxidative Conditions Rosa D., *$Orellana A.
12:20 00751 Rh (I) Catalyzed Cycloisomerization of Oxabicycles Kouchekzadeh Yazdi S., *Webster R., $Lautens M.
12:20 00752 Synthesis of 6-alken-1-ones from Cyclobutyl Allyl Carbonates Chtchemelinine A., *$Orellana A.

The Chemistry and Biology of Natural Products

12:20 00753 Microwave-Assisted, Continuous Flow Organic Synthesis of Benzofused Sultams by a 'Click/Cyclize' Strategy Ullah F., Samarakoon T., Rolfe A., Kurtz R.D., Hanson P.R., *$Organ M.G.
12:20 00754 Novel Triterpenoidal Alkaloids from Buxus natalensis and thier Enzyme Inhibitory Activities Matochko W., James A., *$Ata A., Gengan R.
12:20 00755 Natural Products from Matricaria chamomilla and their Biological Activities Iverson C.D., Yimeng L., *$Ata A.

Nanochemistry

12:20 00756 Modular Construction of DNA Nanotubes of Tunable Geometry, Stiffness, Well-Defined Length, Loading and Selective Release of Cargo Abilities Lo P.K., $Sleiman H.F.
12:20 00757 Fast Assembly of Block Copolymer Achieved by Solvent-assisted Microwave Annealing Zhang X., Harris K.D., Wu N., *Buriak J.M.
12:20 00758 Synthetic Studies Towards the Functionalization of a Tetracyclic Variant of the G^C Motif Alsbaiee A., Borzsonyi G., *$Fenniri H.
12:20 00759 Very Strong Hydrogen Bonding in Double Helical AAA-DDD Complexes Mudraboyina B., Wang H.-B., $Wisner J.A.
12:20 00760 The Hydrogen-bonded Complex of 2,6-Diaminopyridinium Cation with an Azonaphthyridine Wang H.-B., Newbury R., $Wisner J.A.
12:20 00761 New Organic Ligands for Gold Nanoparticles - A Comparative Study *$Eichhorn S.H., Iqbal M., Carmichael T.B., San Juan R.R.
12:20 00762 Expanding the Functionality of Upconverting Nanoparticles through Surface Modifications Boyer J.C., Gates B.D., *$Branda N.R.

Graduate Student Posters - Nanochemistry

12:20 00763 Altering the Physical Properties of Monolayer Protected Gold Nanoparticles Using a Photoswitchable Pyridyl-Azobenzene Hadadpour M., *Workentin M.S.

Modern Physical Organic Chemistry

12:20 00764 Laser Flash Photolysis of Chromophore-functionalized Gold Nanoparticles: Size-dependant Transient Behavior of Triplet Excited State Ismaili H., *Workentin M.S., Kostina S., Guterman R., Leigh W.J.
12:20 00765 Spectroscopic and Binding Studies of Dansyl-based Fluorescent Sensors for Transition Metals *$Al-Sayah M.H., El-Chami T.M., Shehab M.K.
12:20 00766 A Theoretical Study of the Copper (II) Carboxylate-Promoted Aminooxygenation of Unactivated Olefins Belding L., *Dudding T., Paderes M., $Chemler S.
12:20 00767 Asymmetric Ring-closing Metathesis Using Chiral C1-Symmetric Ru-based Catalysts Timperio J., Stenne B., *Dudding T., $Collins S.K.
12:20 00768 Theoretical Studies of the Asymmetric Lithiation of Pyrroloimidazolinones Taban K., *Dudding T., Xu S., Metallinos C.
12:20 00769 Rotational Barriers and Bond Controversy: A Computational Study of 28 Bisaromatic Systems Kamstra R.L., *$Mawhinney R.C.
12:20 00770 Toward the Development of Biocaptors Based on Ionic Liquids Branca M., *Schmitzer A.R., Masson J.-F.

Graduate Student Posters - Modern Physical Organic Chemistry

12:20 00771 A Blue Shifted Violet H-Aggregate That Is Orange Mooi S.M., Heyne B.
12:20 00772 Novel BODIPY Dyes with Tunable Redox-properties and Functionalities for Further Tethering: Preparation, Electrochemical and Spectroscopic Characterization Krumova K., $Cosa G.
12:20 00773 Whilte Light Emission from Cucurbituril Complexes of Acridizinium Cations in Water and Hydrogels Fraser A.J., *$Macartney D.H.
12:20 00774 Towards Water-soluble Peroxyl Radical Clocks Dhanoa R., $Pratt D.A.
12:20 00775 Cucurbit[7]uril Complexes of Flavylium Cations in Aqueous Solution MacGillivray B.C., *$Macartney D.H.
12:20 00776 Synthesis and Physical Characterization of Stable Sulfenic and Selenenic Acids McGrath A.J., $Pratt D.A.
12:20 End of Session


Monday PM

OR2Room 205 C

Carbohydrate Chemistry and Glycobiology (joint with BM5)

Organizer(s) - Mark Nitz
Chair(s) - M. Nitz

13:40 See BM5

18:00 End of Session

OR10Room 206 F

Recent Advances in Organic Electronics (joint with MT6)

Organizer(s) - Thomas Baumgartner; Warren Piers; Rik Tykwinski
Chair(s) - T. Baumgartner; T. Linder

13:40 See MT6

17:40 End of Session

OR11Room 206 B D

Recent Developments in Heterocyclic Chemistry

Organizer(s) - Andre M. Beauchemin
Chair(s) - A. Orellana; G. Belanger

13:40 00950 Radical Relay Cyclizations for Use in Natural Product Synthesis *$Sammis G.M.
14:20 00951 2-Substituted Benzo[b]furans from Phenols, Trichloroethylene and Boronic Acids: Scope and Mechanistic Investigations into the One-Pot Suzuki Coupling/Direct Arylation Geary L.M., *Hultin P.G.
14:40 00952 The Role of Thermodynamics in Palladium-Catalyzed Allylic Amination Dubovyk I., *Pichugin D., $Yudin A.K.
15:00 00953 The Use of Donor-Acceptor Cyclopropanes for the Synthesis of Heterocycles *Pagenkopf B.L.
15:40 Coffee Break
16:00 00954 Metal Catalyzed One Step Synthesis: Developing Direct Approaches to Heterocycles from Basic Building Blocks *Arndtsen B.A.
16:20 00955 So You Think You Can Dance, Pyridine? Rantanen T., *Snieckus V.
16:40 00956 A Concise Route to Dihydrobenzofurans. A Formal Total Synthesis of Lithospermic Acid and a Total Synthesis of 3,8-Dihydroxy-9-methoxypterocarpan Fischer J., Leung A., Savage P., *$Coster M.J.
17:00 00957 Towards the Total Synthesis of Morphine via a Tandem Oxy-cope/claisen/ene Reaction Lepack K., Marcotte J., Barriault L.
17:20 00958 Synthetic Studies on Heterocyclic Natural Products *$Ciufolini M.A.
18:00 End of Session

OR12Room 205 B D

Synthesis and Applications of Boron Compounds (joint with IN11)

Organizer(s) - Robert Batey; Cathleen Crudden

13:40 00959 Probing the Amphotericin B Ion Channel via Iterative Cross-coupling with MIDA Boronates Burke M.
14:20 00960 Cross-Coupling of Secondary Boronic Esters with Retention of Stereochemistry Glasspoole B.W., Holland A., Lu Y., Oderinde M., Laberge V.S., *$Crudden C.M.
14:40 00961 Boronic Acids Beyond Cross-Coupling: Applications in Catalysis and Phase-Switch Synthesis *Hall D.
15:20 00962 The Higer Boraacenes Wood T.K., $Piers W.E., Keay B.A., Parvez M.
15:40 Coffee Break
16:00 00963 Selective Catalysts Inspired by Boron-based Chemical Sensors *$Taylor M.S., Lee D., Newman S.G.
16:40 00964 Catalytic Borylation of C-H Bonds: A Route to Photophysically Interesting Pyrene Derivatives Crawford A.G., Liu Z., Mkhalid I.A.I., Thibault M.-H., Schwarz N., Alcaraz G., Steffen A., Batsanov A.S., Howard J.A.K., Dwyer A.D., Beeby A., Pĺlsson L.-O., Tozer D.J., *Marder T.B.
17:00 Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture

17:40 End of Session


Tuesday AM

OR2Room 205 C

Carbohydrate Chemistry and Glycobiology (joint with BM5)

Organizer(s) - Mark Nitz
Chair(s) - M. Nitz

08:00 See BM5

12:20 End of Session

OR3Room 206 D

Dendritic Macromolecules: From Synthesis to Applications (joint with MS4)

Organizer(s) - TBA
Chair(s) - A. Kakkar

09:00 See MS4

12:20 End of Session

OR4Room 202 C

General

Organizer(s) - Mark S. Taylor
Chair(s) - V. Raj

08:00 01410 Exploiting Reagent Control in Rhodium Catalyzed Ring Opening Reactions of Unsymmetrical Oxabicyclic Alkenes *Webster R., $Lautens M.
08:20 01411 Highly Chemoselective Reductions of Secondary Amides to Aldehydes, Imines and Amines Pelletier G., Bechara W. S., *Charette A.B.
08:40 01412 Microwave Studies on the Enantioselectivity of a Pd-Catalyzed Polyene Cyclization Lucciola D., *$Keay B.A. WITHDRAWN
09:00 01413 Fe-catalyzed Epoxidation of Olefins using Hydrogen Peroxide Hasan K., *$Kozak C.M.
10:00 Coffee Break
10:20 01414 An Efficient, Modular Synthesis of Methyleneindenes Utilizing a Selective Tandem Cross-Coupling of gem-Dihaloolefins Bryan C.S., *$Lautens M.
10:40 01415 Increased Yields and Simplified Purification with a Second Generation Cobalt Catalyst for the Oxidative Formation of Trans-THF Rings Palmer C., Morra N.A., Stevens A.C., Bajtos B., Machin B.P., Pagenkopf B.L.
11:00 01416 Mechanistic Studies and New Reactivity in Palladium(0)-catalyzed Arylation at C(sp3)-H Bonds *Rousseaux S., Chung B., $Fagnou K.
11:20 01417 Recent Advances in the Development of Enantio- and Diastereoselective Palladium-Catalyzed Nitrogen Arylation Reactions Matarazzo A., Alkhouri B., Wylie R.S., *$Viirre R.D.
11:40 01418 Tandem Cyclopropane Ring-Opening/Conia-ene Reactions: An Efficient Route to Heterocyclic Motifs Grover H.K., Lebold T.P., Leduc A.B., *$Kerr M.A.
12:00 01419 Cascade Chemo-and Biocatalysis in Ionic Liquid: One-pot Synthesis of Chiral Biaryl Alcohols Gauchot V., *Schmitzer A.R.
12:20 End of Session

OR7Room 206 B

Nanochemistry (joint with IN7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - U.D. Hemraz; H. Fenniri

08:00 01420 Functional Polymer/Carbon Nanotube Sensors for Ionizing Radiation Detection *Lobez J.M., $Swager T.M.
08:20 01421 Synthesis of Fluorine-Containing Molecular Rotors and Their Assembly on Gold Nanoparticle *$Morin J.-F., Thibeault D., Auger M.
08:40 01422 Bis(Hemicages) as New Motifs for Chemosensors and Molecular Logic Gates St-Pierre G., Fortin D., *$Zysman-Colman E.
09:00 01423 Growth of Gold Nanoparticles via a Photochemical Seeding Approach McGilvray K.L., *Schwartz-Narbonne R., $Scaiano J.C.
09:20 01424 Modulating Molecular Recognition through Strategic Design *$Gibbs-Davis J.M., Lam J., Bhogal R., Tang A.
10:00 Coffee Break
10:20 01425 Three-Dimensional DNA Structures with Moving Parts: Loading and Selective Release of Cargo for Biological and Materials Applications *$Sleiman H., Lo P.K., Aldaye F.A., Yang H., McLaughlin C.K., Hamblin G.D.
11:00 01426 Dialing Up the Power - Reversible "Remote-Control" Photoswitching using Upconverting Nanoparticles Boyer J.C., Carling C.J., Gates B.D., *$Branda N.R.
11:20 01427 Interfacial Photo-Wolff Rearrangement for the Modification of Gold Nanoparticles Snell K.E., Johnson M., *Workentin M.S.
11:40 01428 Design, Synthesis and Characterization of Bio-Inspired Functional Nanostructures *$Voyer N., Otis F., Hartwick K., Racine-Berthiaume C., Arseneault M.
12:20 End of Session

OR8Room 205 B D

Organic Synthesis: Stereocontrol

Organizer(s) - Greg Dake
Chair(s) - A. Orellana

08:00 01429 Iminium Ion Diels- Alder Reactions Toward the Synthesis of Spiro-Prorocentrimine $Evans D.A., Speed A. W. H., Bindschadler P., Pero J., Juhl M., Borg G., Chiu A., Brandl T.
08:20 01430 Enantioselective Desymmetrization of Bicyclic Hydrazines and 7-Azanorbornenes using Chiral Rhodium-NHC Complexes as Catalysts: An Alternative Route to Epibatidine Bexrud J.A., $Lautens M.
08:40 01431 Development of a Lewis Base Catalyzed, Enantioselective Selenolactonization Reaction Collins W., $Denmark S.E. WITHDRAWN
09:00 01432 Total Synthesis of (+)-isatisine A Karadeolian A., *$Kerr M.A.
Alfred Bader Award Lecture

09:20 01433 Design and Stereoselective Synthesis of Medicinal Agents via Chemoenzymatic Methods: The Story of Amarrylidaceae and Morphine Alkaloids and Tamiflu *$Hudlicky T.
10:00 Coffee Break
10:20 01434 Stereomanaged Syntheses of Some Terpenoids and Alkaloids *$Spino C., Dion A., Douville J., Gagnon D., Tremblay F., Allan M., Léveillé P., Joly M.-A.
11:00 01435 Amphidinolide C, Two Ways Morra N.A., $Pagenkopf B.L.
11:20 01436 Cascade of Azomethine Ylide Cycloaddition and Nucleophilic Cyclization: a New Synthetic Approach Toward Daphnilactone B and Congeners *$Bélanger G., Darsigny V., Doré M., Boudreault J., Lévesque F.
11:40 01437 New Advances with Carbene Catalysis *$Scheidt K.A.
12:20 End of Session


Tuesday PM

OR3Room 206 D

Dendritic Macromolecules: From Synthesis to Applications (joint with MS4)

Organizer(s) - TBA
Chair(s) - A. Castonguay

13:40 See MS4

15:20 End of Session

OR4Room 202 C

General

Organizer(s) - Mark S. Taylor
Chair(s) - M. Taylor

13:40 01612 Recent Advances in Cubane Chemistry *$Priefer R.
14:00 01613 The Importance of Dispersion Interactions to Everyday Chemical Applications *Mackie I.D., $DiLabio G.A.
14:20 01614 Photoresponsive Liposomes: Towards the Photoregulation of Membrane Stability Cai J., Moore J., *$Murphy R.S.
14:40 01615 Pyridine-based Salophen Ananalogues: Synthesis, Self-assembly and Molecular Recognition Keyes L., Leung P., Bhagavathy G., *$Petitjean A.
15:40 Coffee Break
16:00 01616 Expedient Synthesis of Novel Bicyclic Peptidomimetic Scaffolds Huot M., $Moitessier N.
16:20 01617 Mimicking the Aromatic Cage: Lessons from Synthetic Hosts Whiting A.L., Neufeld N.M., *$Hof F.
16:40 01618 Carbon Dioxide and Carbon Disulfide Capture by Nitrogen Compounds Ang M.T. C., Heldebrant D., Phan L., *$Jessop P.G.
17:00 01619 Stilbenophanes from 1,2-Bis(isobenzofuranyl)ethene Hannon M., Thibault M., Wichers L., *$Dibble P.W.
17:20 01620 Verdazyl Radicals as Substrates for the Novel Synthesis of (n)-Paracyclophanes Cumaraswamy A.A, *Hamer G.K, $Georges M.K
17:40 01621 Progress Towards the Total Synthesis of Biselides A-D Bajtos B., $Pagenkopf B.L.
18:00 End of Session

OR7Room 206 B

Nanochemistry (joint with IN7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - J.M. Gibbs-Davis; A. Alsbaiee

13:40 01622 DNA Inspired Heterocycles - Two Faces are Better than One *$Perrin D.M., Asadi A.
14:20 01623 Effects of Proximity of Charge, Steric Bulk, and Substituents on the Self-Assembly of Rosette Nanotubes from Twin Base System Hemraz U.D., Yamazaki T., Kovalenko A., *Fenniri H.
15:00 01624 Self-Assembled Immunopolymeric Nanoparticles for Targeted Delivery in Cancer Ho K., Lu J., Owen S., *$Shoichet M.S.
15:40 Coffee Break
16:00 01625 Development of Artificial Double Helical Hydrogen Bonded Complexes Wisner J.A.
The Division of Inorganic Chemistry Award for Graduate Work Lecture

16:40 01626 Novel Photonic Crystal Architectures for Optoelectronics Puzzo D.P., Manners I., $Ozin G.A.
17:20 01627 Fabrication of Hybrid Materials Based on Gold Nanoparticles: Interaction of Carbene-modified Gold Nanoparticles with Carbon Nanotubes & Functionalized Polymers Ismaili H., *Workentin M.S.
17:40 01628 Stimuli-Responsive Gold Nanoparticles with Low Molecular Weight Surface Coatings Lemieux V., *van Hest J.C.M.
18:00 End of Session

OR8Room 205 B D

Organic Synthesis: Stereocontrol

Organizer(s) - Greg Dake
Chair(s) - G. Dake

13:40 01629 Heteroatom-Centered Radical Cyclizations onto Silyl Enol Ethers *$Sammis G.M.
14:20 01967 Enantioselective Ruthenium-Catalyzed Intramolecular Olefin Hydroesterification and Hydroamidation Kim B., $Dong V. WITHDRAWN
14:40 01630 The Bicyclic Thioglycolate Lactam Route to (-)-Puraquinonic Acid Tiong E., *$Gleason J.L.
R. U. Lemieux Award Lecture

15:00 01631 Some Adventures in Methodology and Total Synthesis *$Clive D.L.J.
15:40 Coffee Break
16:00 01632 New Twists in Nazarov Cyclization Chemistry *$Frontier A.J., Huang J., Malona J.A., Bitar A.Y., Vaidya T.
16:40 01633 Towards the Total Synthesis of Vinigrol Poulin J., Grise-Bard C., *Barriault L.
17:00 01634 Cross-Coupling Reactions of Palladium Homoenolates *$Orellana A., Rosa D., Fernandez F.
17:20 01635 Stereocontrolled Synthesis via Cycloaddition and Ring Opening Reactions Lautens M.
18:00 End of Session

OR9Room 205 C

Radiopharmaceuticals (joint with BM12)

Organizer(s) - Neil Vasdev
Chair(s) - N. Vasdev

13:40 See BM12

17:20 End of Session


Wednesday AM

OR4Room 203 D

General

Organizer(s) - Mark S. Taylor
Chair(s) - T. Wood

08:20 01787 Electrophilic Cyclization of Vinylogous Propargyl Acetate-Co2(CO)6 Complexes Yielding 6,7,n-Tricyclic Ring Systems Kolodziej I., $Green J.R.
08:40 01788 Design and Synthesis of Fluorescent Cyclic Peptides Rotstein B.H., $Yudin A.K.
09:00 01789 Stereoselective Synthesis of 5-Membered Nitrogen Heterocycles from Domino Reduction and Cyclization of Azido Carbonyl Compounds Tjeng A.A., $Batey R.A.
09:20 01790 Synthesis of Substituted Indenes from gem Dibromolocyclopropanes via a 2p-4 p Electrocyclization Cascade Reaction Rosocha G.Y., *Batey R.A.
09:40 01791 Regioselective Rhodium(I)-Catalyzed Hydroarylation of Protected Allylic Amines with Arylboronic Acids $Tsui G.C., Menard F., *Lautens M.
10:00 Coffee Break
10:20 01792 Bitumen Upgrading in Supercritical Fluids Brough S.A., Riley S., Curtis G.C., Allen C.L., *$McGrady G.S., Tanhawiriyakul S., Romero-Zerón L., Willson C.D.
10:40 01793 On the Investigation of Factors that Affect N-Heterocycle Dehydrogenation Dean D., Davis B., $Jessop P.G.
11:00 01794 The Novel Synthesis of a Biphenyl-Stacked Cyclophane and its Conformational/Structural Study via 1H NMR Dang J., *Hamer G.K., $Georges M.K.
11:20 01795 Synthesis of a Novel Nonplanar p-Conjugated Macrocycle with a Porphyrin Core Zhao G., *Pollard M. M.
11:40 End of Session

OR5Room 201 E

Liquid Crystalline Materials (joint with MT4)

Organizer(s) - Kenneth Maly

08:40 See MT4

12:20 End of Session

OR7Room 206 B

Nanochemistry (joint with IN7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - J. Rodriguez; J. Veinot

08:00 01796 Synthesis and Chirooptical Properties of Chiral Silver Nanoclusters Cathcart N., Kitaev V.
08:20 01797 Exploring the Chemistry of Gold Monolayer Protected Clusters Dasog M., Hou W., *$Scott R. W. J.
08:40 01798 Selective Dehybridization Induced by Laser on DNA/Au Nanoconjugates Yu H.-Z.
09:00 01799 Transition Metal Nanoparticle Catalysts Stabilized by Functionalized Ionic Liquids Luska K.L., *Moores A.
09:20 01800 Scalable Assemblies of Flexible Semiconductor Nanowires *$Gates B.D., Wang M.C.P., Zhang X.
10:00 Coffee Break
10:20 01801 Nanocrystals as Precursors to Printed Photovoltaics *$Korgel B.A.
11:00 01802 The Influence of the Germanium Precursor on Nanocrystal Formation: Investigating Different R-groups in RGeCl3 Johnson M., $Veinot J.G.C.
11:20 01803 Light Emitting Diode Stimulated Growth of a Rainbow of Silver Nanoparticles Stamplecoskie K.G., *$Scaiano J.C.
11:40 01804 New Insights into the Brust-Schiffrin Au Nanoparticle Synthesis Goulet P.J.G., *$Lennox R.B.
12:00 End of Session

OR8Room 205 B D

Organic Synthesis: Stereocontrol

Organizer(s) - Greg Dake
Chair(s) - G. Sammis

08:00 01805 Unconventional Stille Coupling on a-alkoxystannanes: Stereochemical Outcome and Mechanism Su J., $Chong J.M.
08:20 01806 Hydrogenolysis of Unstrained Carbon-Carbon sigma-Bonds: Stereoselective Entry Into Benzylic Tertiary Centers Nguyen Y., Wilsily A., Jacq J., *$Fillion E.
08:40 01807 Rapid Synthesis of Spiroindanes via NHC-Catalyzed Domino Stetter-Aldol-Michael and Stetter-Aldol-Aldol Reactions *$Gravel M., Sánchez-Larios E., Holmes J.M., Daschner C.
09:00 01808 Enantioselective Catalysis: Desymmetrization of Imides by Catalytic Hydrogenation and a High Turnover Number, Reusable Catalyst for Cycloisomerizations of 1,6-Enynes *Bergens S.H., Takebayashi S., Hass M., Corkum E WITHDRAWN
09:20 01809 Synthetic Studies on Marine Polypropionates Ward D.E.
10:00 Coffee Break
10:20 01810 Design of Acid Catalysis for Polyketide Cascade Synthesis *$Yamamoto H.
11:00 01811 New Classes of Highly Active Non-metallocene Catalysts for Intramolecular Alkene Hydroamination. An Application to the Stereoregulated Synthesis of Xenovenine Jiang T., Lovick H.M., An D.K., Sunsdahl B., *Livinghouse T.
11:20 01812 Controlling Axial Conformation in 2-arylpyridines and 1-arylisoquinolines: Application to the Asymmetric Synthesis of QUINAP by Dynamic Thermodynamic Resolution *Fletcher S.P., $Clayden J.
Merck Frosst Centre for Therapeutic Research Award Lecture

11:40 01813 Chemoselective Macrocyclization Strategies Yudin A.K.
12:20 End of Session

OR9Room 205 C

Radiopharmaceuticals (joint with BM12)

Organizer(s) - Neil Vasdev
Chair(s) - D. Hunter; M. Kovacs

08:00 See BM12

12:20 End of Session

OR13Room 202 D

The Chemistry and Biology of Natural Products (joint with BM13)

Organizer(s) - Nathan Magarvey; Paul Harrison
Chair(s) - N. Magarvey

08:40 01814 Plant Natural Products and their Enzyme Inhibitory Activities *$Ata A.
09:00 01815 Diverse Approaches to Chemoenzymatic Snthesis of (+)-Codeine Piercy T.G., Duchek J., Ilceski D., *$Hudlicky T.
09:20 01816 Investigating Coral Associated Microbes as a Novel Source of Natural Products *$Kerr R.G.
10:00 Coffee Break
10:20 01817 Novel Sponge Sesterterpenoids that Activate the cAMP Cell Signaling Pathway Andersen R.J.
11:00 D. Birchbank

11:20 01818 Two Molecules of Lobophorolide Cooperate to Stabilize an Actin Dimer Using Both Their 'Ring' and 'Tail' Region Allingham J.
12:00 01819 Synthesis and Biological Activity of Kotalanol, a Naturally-Occurring Glucosidase Inhibitor, and its Analogues Pinto B.M.
12:20 End of Session


Wednesday PM

OR4Room 203 D

General

Organizer(s) - Mark S. Taylor
Chair(s) - M. Taylor

13:40 01920 Benzobisoxadisiloles as Synthetic Equivalents of 1,3- and 1,4- Benzdiyne. Synthesis of Oxadisilole Fused Acenes, Acenequinones and Triptycenes *$Lee A. W. M., Pei B-J., Chen Y.
14:00 01921 "Switchable Water": Aqueous Solutions of Switchable Ionic Strength Mercer S.M., $Jessop P.G.
14:20 01922 Reactions of Transient Germylenes with Oxiranes and Thiiranes in Solution Kostina S., *Leigh W.J.
14:40 01923 Investigation of the Asphaltene Aggregation and the Accessibility of Quenchers to Asphaltene Aggregates using Fluorescence Studies Zhang H.T., Li R., *Bohne C., Gray M., Yin C.X.
15:00 01924 Building Parallel Processing into Molecular Logic Gates by Sequential Addition of Receptors *$Magri D.C., de Silva A.P.
15:20 01925 Dicarbazole-conjugated Fullerene Derivatives: A Synthetical Design of Two-photon Absorption Molecules Zeng G.-C., Ouyang X.-H., Zeng H.-P.
15:40 Coffee Break
16:00 01926 A New Class of Self-Immolative Spacers Based on 4-Aminobutyric Acid DeWit M.A., *Gillies E.R.
16:20 01927 Synthesis of Photochromic 1,2-Bis(5-aryl-2-phenylethynylthien-3-yl)hexafluorocyclopentene Derivatives Cai J., Farhat A., *$Murphy R.S.
16:40 01928 Reactions of Transient Silylenes with Alkenes Reid M.E., *Leigh W.J.
17:00 01929 Luminescence and Photochromism of Conjugated Four-Coordinate Polyboryl Compounds Murphy S., Baik C., *Wang S.
17:20 01930 A DFT Study of Reactivity and Selectivity of Aryl-Claisen Rearrangements: Analysis of Various Functionals for the Claisen Rearrangement Ramadhar T.R., *$Batey R.A.
17:40 End of Session


OR4Room 205 B D
General

13:40 01931 Coordination of Triazole-based Chelating Ligands to Ions of Traditional Tetrahedral Geometry Fleischel O, Mignatelli A, Heyer E, *$Petitjean A
14:00 01932 Pyridine-Borane Lewis Pairs: Adducts, Frustrated Lewis Pairs and Catalytic Hydrogenations Geier S.J., Stephan D.W.
14:20 01933 Transition Metal Catalyzed Dehydrogenation of sec-Butylamine-Borane $Mal S.S., *Baker R.T.
14:40 End of Session

OR5Room 201 E

Liquid Crystalline Materials (joint with MT4)

Organizer(s) - Kenneth Maly

13:40 See MT4

17:20 End of Session

OR7Room 206 B

Nanochemistry (joint with IN7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - M. Johnson

13:40 01934 Synthesis and Characterization of Water Soluble Mn doped Silicon Nanoparticles *$Kauzlarich S.M., Ma X., Atkins T.M., Chuqiao T., Louie A.M.
14:20 01935 High Blocking Temperature Nanomagnets: Dysprosium Single-Molecule Magnets *$Murugesu M.
14:40 01936 Colloidal PbS and PbSe Quantum Dots for Near-IR Emission and their Applications van Veggel F.C.J.M.
15:20 01937 Spherical Aggregates of Nanoparticulate Oxides for Water Purification *$Apblett A.W., Kuriyavar S.
15:40 Coffee Break
16:00 01938 Cu7S4 (Roxbyite) Nanocrystals *Siegers C., Goorah V., Guerin G., Petrov S., $Winnik M.A.
16:20 End of Session

OR9Room 205 C

Radiopharmaceuticals (joint with BM12)

Organizer(s) - Neil Vasdev
Chair(s) - D. Abrams; D. Green

13:40 See BM12

17:00 End of Session

OR13Room 202 D

The Chemistry and Biology of Natural Products (joint with BM13)

Organizer(s) - Nathan Magarvey; Paul Harrison
Chair(s) - P. Harrison

13:40 01939 Harnessing Biosynthetic Pathways to Produce Complex Molecules *$Boddy C.
14:20 01940 Precursor-Directed Biosynthesis of Novel Jadomycins and Expansion of the Jadomycin Library Dupuis S.
15:00 01941 Structural and Functional Characterization of JadX, a Protein of Unknown Function in the Jadomycin B Biosynthetic Pathway Robertson A. W., $Jakeman D.L.
15:20 01942 Pramanicin, an Antifungal Natural Product: Synthesis and Biological Testing of Defunctionalized Analogues McIntee J.W., Wynes C.S., *$Harrison P.H.M.
15:40 Coffee Break
16:00 N.A. Magarvey

16:40 01943 Biosynthesis of Conjugated Fatty Acids: Mechanistic Studies Bhar P., Buist P.H.
17:00 01944 The Biosynthesis of Wasalexins and Related Plant Defense Metabolites from Salt Cress, a Cruciferous Plant *$Pedras M.S.C., Yaya E.
17:40 01945 New Approach to the Synthesis of C-1 Analogs of Pancratistatin Vshyvenko S., Collins J., *$Hudlicky T.
18:00 End of Session


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