93rd Canadian Chemistry Conference and Exhibition


Inorganic Chemistry

Sunday AM

INALRoom 205 B D

Rio Tinto Alcan Award Lecture (joint with ICAL)

Organizer(s) - Robert Morris; Nick Toltl

09:15 Introductory Remarks
09:20 00021 How Can One Tell If a Rechargeable Battery Will Last 10 Years - In a Few Weeks? *$Dahn J.R., Smith A.J., Burns J.C., Trussler S.
10:00 End of Session

INPConstitution Hall

Posters

Organizer(s) - Robert Morris
Chair(s) - R. Morris

From 12:20 until 13:40

Poster sessions are from 12:20 - 13:40 and 17:40 - 19:20.

12:20 00022 Complexes of Metal Atoms and Unsaturated Hydrocarbon Molecules:Intra- and Intermolecular Cooperativity of Binding *$Naumkin F.Y.
12:20 00023 Bright Metal-to-Ligand Charge Transfer Phosphorescence in Pt(II) Complexes Promoted by Triarylboron *Hudson Z.M., Sun C., $Wang S.
12:20 00025 Tetrahedral to Octahedral Chirality Transfer via the Disassembly of Diruthenium(II,III) Tetracarboxylates Aquino M.A.S., Vadavi R., Conrad E.D., Arbuckle D.I., Lundrigan T.L.
12:20 00026 [Boratabenzene-phosphole]Li: A Study on Aromaticity of Heteroaromatic Rings *$Fontaine F.-G., Bélanger-Chabot G., Rioux P., Maron L.
12:20 00027 Mechanochemically Assisted Preparation of Lithium Nitridometallates and their Application in Hydrogen Storage Langmi H.W., Culligan S.D., Reddy V.B., *$McGrady G.S.
12:20 00028 Mercury(I) Complexes with Bidentate Iminopyridine Ligands: Synthesis, Spectral Characterization and Structural Analysis *Khalaj M., Dehghanpour S., Mahmoudi A.
12:20 00029 Modelling Infrared Spectra of Phosphorous-based Chemical Nerve Agents Mackie I.D., Petryk M., DiLabio G.A.
12:20 00030 (3-Iminophosphine)palladium(II) Complexes: Active Catalysts for the Intermolecular Hydroamination of 1,2- and 1,3-Dienes Kuchenbeiser G., Shaffer A.R., *$Schmidt J.A. R.
12:20 00031 Chromium Diimine Alkoxide Complexes from Protonolysis of Chromocene Zhou W., *Smith K.M.
12:20 00032 Structural and Catalytic Properties of Ruthenium Piano-Stool Complexes Bearing an Anionic Tripodal Phosphine *$Spivak G.J., Walker J.M., Cox A., Wang R.
12:20 00033 Unexpected Oxygen Extrusion of Tantalum Amidate Complexes Under Reductive Conditions *Horrillo-Martinez P., Patrick B.O., Schafer L.L., $Fryzuk M.D.
12:20 00034 Novel Ferrocene-Containing Ligands Derived From Ferrocenylamine Stanlake L.J. E., *$Stephan D. W.
12:20 00035 Homogeneous Metathesis and its Industrial Application - Still a Contradiction? Schachner J.A., Schaaf P.A., Pretot R., $Limbach M.
12:20 00036 Polynuclear Lanthanides Single-Molecule Magnets with High Anisotropic Barriers *Long J., Lin P.-H., Korobkov I., Wernsdorfer W., $Murugesu M.
12:20 00037 Synthesis and Redox Chemistry of Ruthenium Complexes of Verdazyl Radicals and their N-Alkylated Analogues $Johnston C., McKinnon S.D. J., Schwantje T.R., *Hicks R.G.
12:20 00038 Charge Density Studies of Al-based Hydrogen Storage Materials *Sirsch P., Che F.N., Titah J.T., $McGrady G.S.
12:20 00039 Transition Metal Complexes of 2-Formylpyridinethiosemicarbazone (FpyTSC), X-Ray Crystal Structures of [Pd(FpyTSC)(PPh3)]PF6 and Pd(FpyTSC)(SCN) Elsayed S.A., El-Hendawy A.M., Mostafa S.I., Butler I.S.
12:20 00040 Synthesis and Characterization of a Series of Halide-bridged Multinuclear Iron(II) and Cobalt(II) Diamido Complexes and Dinuclear, High-Spin Fe(II) and Co(II) Alkyl Derivatives Moatazedi Z., *$Leznoff D.B.
12:20 00041 Toward Ruthenium(II) Tandem Cyclopropanation Catalysts Lummiss J., $Fogg D.E.
12:20 00042 Novel Atomic Layer Deposition Precursors for Group 11 Thin Metal Films Kurek A., *$Barry S.T.
12:20 00043 Comparative Study of Cadmium(II) Selenourea and Thiourea Complex Formation Amini Z., *Jalilehvand F.
12:20 00044 Late Transition Metal Complexes and Reactivity of Novel Cyclic Phosphinimines Brown C.C., $Stephan D.W.
12:20 00045 Cadmium Thiophenolate Complexes as Precursors to Mesostructured CdS Levchenko T.I., Huang Y., Corrigan J.F.
12:20 00046 Long Range Sensitization of Photolabile Complexes in Multimetallic Assemblies on Metal Oxide Surfaces Rahman M.A., *$Thompson D. W.
12:20 00047 Four-coordinated Zinc(II) Complexes with Iminopyridine Ligands *Khalaj M., Dehghanpour S., Mahmoudi A., Nasrollahzadeh M.
12:20 00048 High-Throughput Technology In Academic Research Clément R.C.
12:20 00049 Synthesis of Chiral Chelating Ligands derived from Amino Acids Etkin N.
12:20 00050 Synthesis, Characterization, and Structures of Copper (I) Complexes with N,N'-bis [1-(4-chlorophenyl)ethylidene]ethane-1,2-diamine and N,N'-bis[1-(4-nitrophenyl) ethylidene]ethane -1,2-diamine *$Mahmoudi A., Dehghanpour S., Sadeh S.
12:20 00051 Activation of Small Molecules via Main Group Radicals $Giffin N.A., Hendsbee A.D., Rogers T.D., *Masuda J.D.

Graduate Student Posters - General IN

12:20 00054 Transition Metal Complexes of Some Ditopic, Tetratopic and Hexatopic Ligands Towards Large [nxn] Square Grids (n = 2 - 6) Elliott A.S., *Thompson L., Dawe L.N.
12:20 00055 P-X Bond Formation Reactions of Electrophilic Phosphinidene Complexes $Vaheesar K., Bolton T.M., East A.L.L., Rakesh A.R., *Sterenberg B.T.
12:20 00056 Layered Inclusion Compounds of Leu-Ala Dipeptide with Small Organic Molecules Yazdani A., Chirmanov V.V., *Soldatov D.V.
12:20 00057 Biopolymer Chirality at Work! Babin M., Fontaine F.-G., Gagnon J.
12:20 00058 Magnetic Properties of 1,2,3,5-diselenadiazolyl Coordination Complexes of First Row Transition Metal Ions MacDonald D.J., $Preuss K.E., Clerac R.
12:20 00059 Unexpected Catalytic and Stoichiometric Reactivity of Novel Mo(IV) Imido Silylhydrides Khalimon A.Y., Nikonov G.I.
12:20 00060 Continuing the Exploration of the Heterocyclic Chemistry of Group 14 Elements: Pyrrolides and Indolides Poisson J., Wharf I., Bohle D.S., Barsan M. M., Gu X., Butler I.S.
12:20 00061 Metal-Free Dehydrocoupling to Yield Distannanes Khan A., Gossage R., Foucher D.
12:20 00062 Design of New Polymetallic Free Radical Complexes Revunova K., Adugna S., *$Lemaire M.T., Jenkins H.A.
12:20 00063 Photoinduced EPT in Re-based Chromophore Quencher Assemblies Dongare P., $Thompson D.W.
12:20 00064 Excited States in Polymetallic Clusters: New Scaffolds for Excited States within Spatially-Confined Ligand Systems Smith S.R., *$Thompson D. W.
12:20 00065 Modification of Polymers Using C-H Activating Transition Metal Catalysts McArthur S., *$Baird M.C.
12:20 00066 Chromophore Design: Can One Control Vibrational Modes in MLCT Excited State Decay? Khan M.S., *Poirier R.A., $Thompson D.W.
12:20 00067 Ester Hydrogenation Reactions Catalyzed by Ruthenium Complexes Jaksic B.E., *$Baird M.C.
12:20 00068 NMR Studies of the Chemistry of Alkyl Alkene Complexes of the Type [Cp2M(Me)(alkene)]+ (M = Ti, Zr) Dunlop-Briere A.F., Sauriol F., Sonnenberg J.F., *$Baird M.C.
12:20 00069 Approaches to Metcars Synthesis Fowler K.G., Fraser A. W., *$Baird M.C.
12:20 00070 Synthesis, Characterization and Properties of Three-Coordinate Boron based 8-Hydroxyquinoline Ligands Zlojutro V., Sun Y., *Wang S.
12:20 00071 Selective Oxidation of Crotyl Alcohol Using Au-Pd Core-Shell Nanoparticles Balcha T., Strobl J., Scott R.W.J.
12:20 00072 Reactivity of Platinum Complexes Containing a Pt-Cl-B Interaction with Borabenzene Barnes S.S., *Fontaine F.-G., Maron L.
12:20 00073 A Ditopic Ligand for "Needle and Thread" Coordination Frank N.C., $Loeb S.J.
12:20 00074 The Synthesis of Phosphinimine Containing Pincer Ligands: Metal Complexation and Unexpected Ligand Reactivity Sgro M.J., $Stephan D. W.
12:20 00075 Rotaxanes Containing Functional Crown Ethers: The Synthesis of Inverse Metal-Organic Rotaxane Frameworks (i-MORF) Mercer D.J., *Loeb S.J
12:20 00076 A Polynuclear Dysprosium(III) Single-Molecule Magnets with a Large Anisotropic Barrier Lin P.-H., Burchell T.J., Ungur L., Chibotaru L.F., Wernsdorfer W., Murugesu M.
12:20 00077 Synthesis and Reactivity of Homoleptic Tri-Alkyl Lanthanide Complexes Using N,N-Dimethylbenzylamine as a Ligand Scaffold Behrle A.C., $Schmidt J.A.R.
12:20 00078 Early Transition Metal Catalysts Incorporating N,O-Chelating Ligands for the Catalytic Synthesis of Amines Payne P.R., *$Schafer L.L.
12:20 00079 Ferrocene Based Dithiolate Ligand for Nanocluster Assembly Khalili Najafabadi B., *Corrigan J.F.
12:20 00080 Synthesis of Amine Stabilized Nanoparticles to be used in Ligand Exchange Reactions Rak M.J., Luska K.L., Moores A.
12:20 00081 Cationic Complexes of Silicon(II) and Tin(II) Avery J.C., Rupar P.A., $Baines K.M.
12:20 00082 Phosphonium Ionic Liquids as Metal Extractants Dube J.W., Ragogna P.J.
12:20 00084 Screening of Mono-, Bi- and Trimetallic Heterogeneous Nanoparticle Catalysts Supported on Mixed-Metal Oxides for Polyaromatic and Hetercyclic Aromatic Hydrogenation Activity Dehm N.A., $Buriak J.M., Clement R.
12:20 00085 A New Tetrahedral Ligand for Metal-Organic Frameworks Caputo C.B., $Loeb S.J.
12:20 00086 Palladium b-Diiminate Chemistry: Reactivity with Donor Ligands, and Transmetallation Reagents Annibale V.T., *$Song D.
12:20 00087 Late Transition Metal Complexes of n3-Coordinated Vinylboranes Kolpin K.B., *Emslie D.J.H.
12:20 00088 Charge Transport and Charge Transfer Parameters of Organic Redox Shuttles for Lithium Batteries Trinh N.D., *Schougaard S.B., Liang G.
12:20 00089 Stability Study of Chemical Deinsertion of Lithium in LiCoO2 and LiMn2O4 Lepage D., *Schougaard S.
12:20 00090 Studies of Iron Polyfluorometallacycle Complexes Enroute to the "Green" Catalytic Synthesis of Hydrofluorocarbons Granville S.L., *Baker R.T.
12:20 00091 High-Valent Polyfluoronickelacycles: Intermediates for Green Routes to Hydrofluorocarbons Hunter N.M., Farhat A., Pell W., Korobkov I., *$Baker R.T.
12:20 00092 Spectral and Electrochemical Behavior of Scorpionate Complexes - Towards an Electrochemical Molecular Switch Vachon J., Majoral M., Ayme-Perrot D., *Schougaard S.B.

Biodegradable / Green Polymers: Catalysis to Materials

12:20 00093 Silicone Polyesters and Polyamides Frampton M.B., Subczynska I.T., *$Zelisko P.M.

Graduate Student Posters - Biodegradable / Green Polymers

12:20 00094 Synthesis and Characterization of Stereocontrolled Biodegradable Polymer Stars *Shaver M.P., Cameron D.A.
12:20 00095 Yttrium Amidate Complexes for the Catalytic Synthesis of Biodegradable Polymers Thomson J., *$Schafer L.

Interplay of Ligand Design and Small Molecule Activation

12:20 00096 Toward Molecular 'S4'Mo with Two Open Sites: Nitrile Complexes of Molybdenum Bisdithiolenes Gapinska A., *Fekl U.
12:20 00097 Transfer Hydrogenation of Ketones Using Iron(II) Catalysts: Ligand Effect In H2 Transfer Mikhailine A.A., *Lagaditis P.O., Lough A.J., $Morris R.H.
12:20 00098 Ligand-Centered Alkene Reactivity of Metal Trisdithiolenes and Applications to Metal Dithiolene Synthesis $Nguyen N., Harrison D.J., *Fekl U.
12:20 00099 Synthesis, Characterization and Reactivity of a Novel Arylspiroboronate Ester Melanson J.A., Halcovitch N.R., Vogels C.M., Decken A., *Westcott S.A.

Graduate Student Posters - Interplay of Ligand Design and Small Molecule Activation

12:20 00100 Synthesis and Reactivity of Late Metal Complexes Featuring New PSiN Mixed Donor Tridentate Silyl Ligands Ruddy A.J., $Turculet L.

Main Group Chemistry

12:20 00101 Investigating Allylindium Structure and Reactivity Allan C.J., *$Macdonald C.L.B.
12:20 00102 Stabilization of Multiple Metal-Metal Bonds with New Bulky Ligand Frameworks Caputo C.A., $Power P.P.
12:20 00103 Synthesis in Supercritical Water, X-ray Structural Analysis and Vibrational Spectra of Some New Metal Phosphates Assaaoudi H., Butler I.S., Kozinski J.A.
12:20 00104 Recent Developments in Neutral Low-Oxidation State Phosphorus Oligomers Farrar G.J., *Macdonald C.L.B.
12:20 00105 Addition Polymerization of a Silene *Guo J., Pavelka L., $Baines K.
12:20 00106 A New Dithiazolyl Fused o-Quinone; A Potential Spin Bearing Ligand Smithson C.S., *$Preuss K.E.
12:20 00107 Magnetic Anisotropy in a Radical Ferromagnet Winter S.M., *Oakley R.T., Hill S., Datta S.
12:20 00108 Reactivity of Main Group Radicals with N-Heterocycles and Elemental Phosphorus Giffin N.A., Rogers T.D., Hendsbee A.D., $Masuda J.D.
12:20 00109 New Thiophene Substituted N-Heterocyclic Phosphenium Cations Price J.T., *Jones N.D., $Ragogna P.J.
12:20 00110 Pnictinopnictonium Cations: New Interpnictogen Frameworks Exploiting P[Pn Coordination Chemistry Pickup J.E., Conrad E., Burford N., McDonald R., Ferguson M.J.
12:20 00111 Towards Four-Membered N-Heterocyclic Phosphenium Cations Supported by Dianionic Guanidinate Ligands Brazeau A.L., Jones N.D., *$Ragogna P.J.
12:20 00112 The Development of New Strategies for the Stabilization of Novel Inorganic Bonding Environments *$Al-Rafia S.M. Ibrah, Rivard E.
12:20 00113 Metal-Free Catalytic Hydrogenation of Imines by Frustrated Lewis Pairs Greenberg S., *Graham T. W., Chase P.A., $Stephan D. W.
12:20 00114 Microwave Assisted Synthesis of Nanocatalysts and Nanoparticles $Porter K.A., *Barnhardt E.K.

Graduate Student Posters - Main Group Chemistry

12:20 00115 Semi-quinone Bridged Bisdithiazolyls Yu X., Mailman A.M., *Oakley R.T.
12:20 00116 Sulfur(IV) Chemistry: Adducts of SF4 with Nitrogen-Bases and Phase Properties of SF3+ Salts Chaudhary P., *$Gerken M., Hazendonk P., Mercier H.P.A.
12:20 00117 Synthesis and Characterization of a New Thiadiazolo- Fused p-Semiquinone Morgan I.S., Jennings M., *$Preuss K.E.
12:20 00118 Crown Ether Complexes of Low Valent p-Block Elements RoyChowdhury R., *$Macdonald C.L. B
12:20 00119 Room Temperature Reduction of CO2 to Methanol by Al-Based Frustrated Lewis Pairs and Ammonia Borane Menard G., $Stephan D.W.
12:20 00120 The Isolation and Reactivity of New Sulfur(II) Cations Martin C.D., Ragogna P.J.
12:20 00121 Synthesis of Neutral Heteroles Containing Group 13 Elements Gezahegn S., *$McWilliams A.R.
12:20 00122 Synthesis and Characterization of Pyridin-4-one Bis-Dithiazolyl Neutral Radical Ligand Carello C.E., *$Preuss K.E.

N-Heterocyclic Carbene Chemistry

12:20 00123 New Pincer Complexes of Nickel $Bertoli M.
12:20 00124 New Thiophene Analogues of Bis(imino)acenaphthene and their NHC Complexes Price J.T., *Jones N.D., $Ragogna P.J.
12:20 00125 Coordination of Imino-N-Heterocyclic Carbenes to Early Transition Metals Larocque T., *$Lavoie G.G.
12:20 00126 Synthesis of Rhodium N-Heterocyclic Carbene Complexes and their Reactions with Oxygen Keske E., Praetorius J.M., *$Crudden C.M.
12:20 00127 Coordination Study of Imino-N-Heterocyclic Carbene Ligands to Group 10-12 Transition Metals Badaj A.C., *$Lavoie G.G.
12:20 00128 Coordination Study of Bis(Imino)-N-Heterocyclic Carbene Pincer (NCN) Ligand to Late Transition Metals Al Thagfi J., *$Lavoie G.G.

Rings, Chains and Polymers with Inorganic Elements

12:20 00129 Perfluorinated Polystannanes Miles D., Foucher D.
12:20 00130 Pyridine Donor Stabilized Aluminum and Gallium Compounds for the Synthesis of [1]FCPs Breit N.C., Ancelet T., *Müller J., Quail J.W., Schatte G.
12:20 00131 Self-assembly of Oligomeric Cyclic bis(dipyrrinato) Metal Complexes Miao Q., *Dolphin D.
12:20 00132 Dithienophosphole as Building Block for p-Conjugated Oligomers Durben S., *$Baumgartner T.
12:20 00133 Poly(methylenephosphine)-Polystyrene Copolymers in Transition Metal-Catalyzed Organic Reactions Krummenacher I., $Gates D.P.
12:20 00134 The Serendipitous Formation of High Order Ruthenium Chloride Clusters by Laser Desorption Ionization of RuCl33H2O Boncheff A.G., $Monteiro M.A.

Graduate Student Posters - Rings, Chains and Polymers with Inorganic Elements

12:20 00135 Exploring the Reactivity of RECl2 (E = Al/Ga) to Prepare New Ferrocene Derivatives Bagh B., Lund C.L., *Müller J., Schatte G.

Symposium in Honour of Dick Puddephatt

12:20 00136 Synthesis and Reactivity of RCpNiLL' Complexes: Steric and Electronic Effects of the Ligands Chadha P., Ragogna P.J.
12:20 00137 Insights On Metallation of Pincer-Type Ligands by Nickel(II) Vabre B., *$Zargarian D., Ess D.
12:20 00138 Efficient Production of Hydrido(carbonyl) Ruthenium Complexes from 1st and 2nd-Generation Grubbs Catalysts Beach N.J., $Fogg D.E.
12:20 00139 POCN(amino)-Type Pincer Complexes of Nickel(II) and Nickel(III) Spasyuk D.M., *$Zargarian D.
12:20 End of Session


Sunday PM

IN6Room 206 A

Main Group Chemistry

Organizer(s) - Andrew McWilliams
Chair(s) - A. McWilliams

13:40 00318 Strong C-centered Bases: From Highly Anionic Coordination Complexes of Organometallic Reagents to Novel Reactions of N-Heterocyclic Carbenes Clyburne J.A.C.
14:20 00319 Click-type Reactions Using Strained Phosphorus Heterocycles Streubel R.
15:00 00320 Synthesis and Structural Characterization of 1,2,4,6-selenatriazines and 1,2,4,6-selenatriazinyls *$Boeré R.T., Zhou J., Roemmele T.L.
15:20 00321 Heterocyclic Bis-1,2,3-dithiazoles with Zwitterionic Ground States and Related Radicals Mailman A., Winter S.M., Roberts R.J., Cvrkalj K., Yu X., *Oakley R.T.
15:40 Coffee Break
16:00 00322 Zinc Chalcogenolate Complexes as Molecular Precursors to Manganese (II) Containing Ternary Nanoclusters $Khadka C.B., *Corrigan J.F.
16:20 00323 Formation and Oxidation of Trichalcogeno PCP-Bridged Ligands Konu J., *Chivers T.
16:40 00324 A Radical Approach to Main Group Materials Oakley R.T.
17:20 00325 The Addition of Amides to Group 14 (Di)metallenes Hardwick J.A., $Baines K.M.
17:40 00326 The Oxide Fluoride Chemistry of Xenon(IV) Brock D.S., $Mercier H.P. A., Schrobilgen G.J.
18:00 End of Session

IN8Room 206 C

N-heterocyclic Carbene Chemistry

Organizer(s) - Dmitri Goussev
Chair(s) - M.C. Organ

13:40 00327 Platinum Group Metal Complexes Bearing a Primary Amino-functionalized N-Heterocyclic Carbene as Ligand-metal Bifunctional Catalysts in the Hydrogenation of Ketones O W. W. N., Lough A.J., $Morris R.H.
14:00 00328 Unexpected Reactivity of a Phosphaalkene with an N-Heterocyclic Carbene *$Gates D.P., Bates J.I., Kennepohl P.
14:20 00329 Thermally Robust Ruthenium Phosphonium Alkylidene Catalysts *Leitao E.M., $Piers W. E.
14:40 00330 A Two-Step Synthesis of Chiral Pyrroloimidazol(in)ylidene Precatalysts: Implications for Catalyst Development John J., Xu S., Akong R., *Metallinos C.
15:00 00331 The NHC Off-Switch on Grubbs' Metathesis Catalysts Diver S.T., Keister J.B.
15:40 Coffee Break
16:00 00332 Expanding the Limits: Tuning the Electronic Properties of N-Heterocyclic Carbenes Hobbs M.G., Krahulic K.E., Welsh P., Knapp C.J., Forster T.D., Tuononen H.M., Ziegler T., *$Roesler R.
16:40 00333 NHC and Related N-Heterocyclic Systems: Building Blocks for Multidentate Ligands and New Modified Ring Structures *Ganter C., Willms H., Hildebrandt B., Braun M.
17:00 00334 Chiral Non-Symmetric NHC-Carbene Complexes with Dioxolane Backbone. Heterogenization on Structured Mesoporous Materials and Catalytic Applications Hernández M., *Sánchez F., Villaverde G., Corma A.
17:20 00335 Reactivity of A Golden Synthon *$Nolan S.P., Ramon R.S., Gaillard S, Slawin A.M.Z., Nun P., Boogaerts I.
18:00 End of Session

IN10Room 205 A

Seminar in Honour of Dick Puddephatt

Organizer(s) - Datong Song
Chair(s) - D. Fogg

13:40 00336 Carbon-Hydrogen or Silicon-Carbon Bond Activation by Organoplatinum Complexes *$Puddephatt R.J., Safa M.
14:00 00337 The Hidden Face of the Pd3(dppm)3(CO)n Clusters (n = +2, +1, 0, -1, -2) *$Harvey P.D., Mugnier Y., Lucas D., Boeré R., Jugé S.
14:20 00338 Recent Adventures in Photoluminescent d10 Complexes *$Eisenberg R., Manbeck G.F., Brennessel W., Evans C.
15:00 00339 Adventures with Platinum-based Metallacycles: Syntheses, Luminescence Properties, and Oxidative Addition Reactions Involving 9,10-Dihydroplatinaanthracenes *$Fekl U., De Crisci A.G.
15:20 00340 Oligonuclear Complexes for the Photochemical Production of Hydrogen *$Hanan G.S., Cooke M. W., Hirahara M., Sakai K.
15:40 Coffee Break
16:00 00341 Recent Advances in Homogeneous Oxidation of Hydrocarbons with Platinum and Palladium Complexes *$Bercaw J.E., Labinger J.A.
16:40 00342 Activation of a C-H bond of Trimethylphosphine to Form a Dimeric P, C-Bridged Bimetallic Palladium Complex *$Cavell R.G., Ma G.-B., McDonald R.
17:00 00343 The Reactivity of the Complex [PtMe2(1,2-di-2-pyridylethane)] Safa M.S., *Jennings M.C., $Puddephatt R.J
17:20 00344 Reactions of Late Transition Metal Complexes with Molecular Oxygen Goldberg K.I.
18:00 End of Session

IN11Room 205 B D

Synthesis and Applications of Boron Compounds (joint with OR12)

Organizer(s) - Robert Batey; Cathleen Crudden

13:40 See OR12

18:00 End of Session


Monday AM

IN3Room 202 C

General

Organizer(s) - Robert Morris
Chair(s) - S. Gorelsky

08:00 00547 A New Family of Phosphorescent Heteroleptic Iridium Complexes Based on Aryltriazole Cyclometallating Ligands Ladouceur S., Mathieu F., Fortin D., *$Zysman-Colman E.
08:20 00548 Synthesis and Characterization of Inorganic Dyads Utilizing Charge-separation, with Potential Aplications for Photo-splitting Water or Information Storage Dares C., *Lever A.B.P.
08:40 00549 Perturbation of Mixed-Valence Properties by Azodicyd Bridging Ligands in [{Ru(trpy)(bpy)}2(l-R2R'2-azodicyd)]3+ Complexes $Choudhuri M.M.R., Behzad M., Al-Noaimi M., *Crutchley R.J.
09:00 00550 Hybrid Organic-Inorganic Chromophores for Light-Harvesting Applications Koivisto B.D., Robson K.C. D., *$Berlinguette C.P.
09:20 00551 Triplet State Chromophores in Homogeneous Photocatalytic Reduction of Water *McCormick T.M., Calitree B., Orchard A., Detty M., $Eisenberg R.
09:40 00552 Utilization of Orthometalated Acetophenone Imine Derivatives in Group 4 and 5 Metal Chemistry Beck J.F., Neshat A., Baiz T.I., *$Schmidt J.A. R.
10:00 Coffee Break
10:20 00553 Structure and Electronic Properties of a Niobium(IV)-oxo Complex Incorporating a Redox-active Phthalocyanine Ligand Wong E. W. Y., Walsby C.J., Storr T., *$Leznoff D.B.
10:40 00554 Luminescence Spectroscopy of Square-planar Platinum(II) and Palladium(II) Complexes: Molecular Electronic Structure and Intermolecular Effects Reber C.
11:00 00555 Novel Rare-Earth (La, Sm, Gd, Ho) Antimony Suboxides for Thermoelectricity Wang P.L., Forbes S.H., Kolodiazhnyi T., *$Mozharivskyj Y.
11:20 00556 The Synthesis and Characterization of a Benzoxazolyl-1,2,3,5-dithiadiazolyl Radical (boaDTDA) and Corresponding Mn(II)(hfac)2(boaDTDA) Complex Fatila E.M., *$Preuss K.E., Clerac R., Jennings M., Assoud J.
11:40 00557 The Rhodium Tris-Semiquinone Redox Series; A Density Functional Theory Analysis of Broken Symmetry, Mixed Valence, Species Dodsworth E.S., Tse Y.-H., Lever A.B.P.
12:00 00558 Metal-Radical Approaches Toward High-Spin Molecules with Isolated Ground States *$Lemaire M.T., Revunova K., Adugna S. WITHDRAWN
12:20 End of Session

IN6Room 206 A

Main Group Chemistry

Organizer(s) - Andrew McWilliams
Chair(s) - G. Briand

08:00 00559 Solvolytic Behaviour of F3S«NXeF+ in Anhydrous HF and the Formation of Novel Cations Containing the F4S=N- Ligand Smith G.L., Mercier H.P. A., *$Schrobilgen G.J.
08:20 00560 Investigations of Azobenzenes Functionalized with Heavy Main-Group Elements Elder P.J.W., *Varga-Baca I.
08:40 00561 Complexes of Low Valent Main Group Species with Crown-Ethers and Related Ligands *$Macdonald C.L.B., Bandyopadhyay R., Cooper B.F.T., Friedl W.W., Rupar P.A., Ragogna P.J., Baines K.M., Allan C.J.
09:20 00562 Pnictinopnictonium and Pnicteniumpnictonium Cations $Conrad E., *Burford N.
09:40 00563 Synthesis of Dicationic Group 16 Carbene Analogues Dutton J.L., $Ragogna P.J.
10:00 Coffee Break
10:20 00564 The Involvement of Acidic Impurities in the Chemistry of Chlorophosphazenes *$Tessier C.A., Tun Z.-M., Panzner M.J., Medvetz D.A., Savant D., Scionti V., Rinaldi P.L., Wesdemiotis C., Youngs W.J.
10:40 00565 Theoretical Approach to Understanding the Properties of 5,5'-bis(1,2,3,4-trithiazolium) Dication in (CNSSS)2[A]2 (A = AsF6-, SbF6-, Sb2F11-). A Rare Example of a Simple Non-Sterically Hindered Main Group Diradical that Retains its Paramagnetism in the Solid State Altmannshofer S., Cameron T.S., Decken A., Grein F., Knapp C., *Passmore J., Rautiainen J.M., Scherer W., Shuvaev K.V., Thompson R.C., Wood D.J.
11:00 00566 The Role of Polyphosphorus Units in Transition Metal Chemistry *Scheer M., Dielmann F., Schindler A., Welsch S.
11:40 00567 Synthesis and Applications of Fluorinated Phosphonium Ionic Liquids *$Ragogna P.J., Tindale J.J., Magdzinski E.
12:20 End of Session

IN8Room 206 C

N-heterocyclic Carbene Chemistry

Organizer(s) - Dmitri Goussev
Chair(s) - R. Roesler

08:20 00568 New Stable Carbon-Based Ligands, Novel Catalytic Reactions *$Bertrand G.
09:00 00569 A New Class of N-Heterocyclic Carbenes: N,N'-Diamidocarbenes: Synthesis and Reactivity Hudnall T. W., *$Bielawski C. W.
09:20 00570 Synthesis, Structure and Reactivity of Iridium NHC Pincer Complexes Schultz K.M., Kaminsky W., Goldberg K.I., *Heinekey D.M.
09:40 00571 Synthesis of a Bicyclic Palladacycle with an Abnormal NHC Palladium Bond from a Task Specific Ionic Liquid *$Singer R.D., Naik P.U., Farrell J., Trider C.-L., Bucar D.K., MacGillivray L.R., Pye C.C.
10:00 Coffee Break
10:20 00572 Challenging the Norm: Abnormal Carbene Complexes, Their Reactivity and Their Impact on Catalysis Krüger A., Heckenroth M., Iglesias M., Lalrempuia R., *Albrecht M.
11:00 00573 Rh Complexes of N-Heterocyclic Carbenes and their Reactions with Small Molecules *$Crudden C.M., Praetorius J.M., Cipot-Wechsler J., Keske E., Kennepohl P.
11:20 00574 Relating Structure to Activity: Why NHC Ligands are Ideal for Cross Coupling *$Organ M.G., Çalimsiz S., Sayah M., Hoi K.H., Hopkinson A.C., Froese R.D.J., Mallik D., Dowlet M., Hadei N., Hunter H.N.
11:40 00575 C2-symmetric di-N-Heterocyclic Carbene (NHC) Ligands and their Application in Metal Catalyzed Enantioselective Synthesis *$Veige A.S., Jeletic M.S., Lowry R.J., Jurcak M., Abboud K.A.
12:20 End of Session

IN10Room 205 A

Seminar in Honour of Dick Puddephatt

Organizer(s) - Datong Song
Chair(s) - U. Fekl

08:00 00581 New POCOP-Type Pincer Complexes of Nickel Spasyuk D.M., *$Zargarian D.
08:20 00577 Synthesis and Reactivity of New Group 10 Metal Silyl Pincer Complexes Mitton S.J., $Turculet L.
08:40 00578 Thermodynamics of Carbon-Hydrogen and Carbon-Carbon Bond Activation at Rhodium and Nickel *$Jones W.D.
09:20 00579 Thiophene Activation: Could Quinoline Functionality Help? Tan R., *Song D.
09:40 00580 From Lithium to Uranium with Old and New Diamido-type Ligands Leznoff D.B.
10:00 Coffee Break
10:20 00576 Dimeric POCN(amido)-Type Pincer Complexes of Nickel: Synthesis, Reactivities, and Redox Chemistry Spasyuk D.M., *$Zargarian D.
10:40 00582 Metal Templated Cycloaddition: a 4+2 Cycloaddition of an Alkyne with a Diyne Templated by Mixed Metal Templates *$Sterenberg B.T., Tsui J.A.
11:00 00583 Logical Approaches to High Nuclearity Square [nxn] Poly-metallic Grids; Successes, Properties and Prospects Thompson L.K., Dawe L.N., Shuvaev K.V.
11:20 00584 Silver(I) Ethynediide and Ethynide Complexes Assembled with Multinuclear Metal-ligand Supramolecular Synthons *$Mak T.C.W.
11:40 00585 Silver(I) Coordination Compounds with Heteroaromatic Dinitrile Ligands: Structural Variety by Heteroatom Identity and Orientation of Ligand *$MacKinnon C.D., Andreychuk N.R., D'Aleo D.N., Parent S.L.M., Assoud A.
12:00 00586 Thermal Decomposition Mechanisms for Metal Films: Applications to CVD *$Barry S.T.
Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture - Monday, 17:00, Room 205 B D

12:20 End of Session

IN11Room 205 B D

Synthesis and Applications of Boron Compounds (joint with OR12)

Organizer(s) - Robert Batey; Cathleen Crudden

08:00 See OR12

12:20 End of Session


Monday PM

IN2Room 205 A

Bioinorganic Chemistry (joint with BM1)

Organizer(s) - Deborah Zamble
Chair(s) - D. Zamble

14:00 See BM1

Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture - Monday, 17:00, Room 205 B D

17:00 End of Session

IN3Room 202 C

General

Organizer(s) - Robert Morris
Chair(s) - B. Lever

13:40 00903 Catalytic Hydrosilylation of Nitriles and Pyridines Gutsulyak D.G., *$Nikonov G.I.
14:00 00904 Chiral Tantalum and Zirconium Amidate Complexes: Applications in Catalytic Enantioselective Synthesis of Amines Ayinla R.O., Gibson T., $Schafer L.L.
14:20 00905 DFT Molecular Dynamics Simulations of the Olefin-Coordinated Zirconocene-Borate Ion Pair Rowley C.N., *$Woo T.K.
14:40 00906 Novel Reactions and Intermediates in Titanocene Chemistry: Intramolecular 1,5-s Bond Metathesis via e-Agostic Interactions; Formation of a Highly Novel, Non-fluxional b-Agostic Alkyltitanocene Complex *$Baird M.C., Sauriol F., Sonnenberg J.F., Chadder S., Dunlop-Brière A.F., Budzelaar P.H.M.
15:00 00907 Diverging Chemistry of Cp2M(Me)(CH2=CMeiBu)+ Complexes (M = Ti, Zr) *Budzelaar P.H.M., Baird M.C.
15:20 00908 Ditopic Carbo- and Thiocarbohydrazine Ligands: Towards New Assembly of Polymetallic Square Grid-based Compounds Dul M.-C., Tandon S.S., Lee J.L., Dawe L.N., *Thompson L.K.
15:40 Coffee Break
16:00 00909 Computational Insights into Metal-catalyzed Direct Alkylation and Arylation Reactions *$Gorelsky S.I.
16:20 00910 Exploring the Utility of P,N Ligands in Chemoselective Buchwald-Hartwig Aminations Tardiff B.J., *Stradiotto M.
16:40 00911 Luminescence Sensing in Solution and the Solid State: Triarylboron Complexes of Pt(II) Acetylide Sun C., Hudson Z.M., *$Wang S.
Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture - Monday, 17:00, Room 205 B D

17:00 End of Session

IN6Room 206 A

Main Group Chemistry

Organizer(s) - Andrew McWilliams
Chair(s) - C. MacDonald

13:40 00912 Stabilizing Small-Ring Allenes: Metal Complexes of 1,2-cyclopentadiene Tuononen H.M., Hänninen M. M., Peuronen A.
14:00 00913 Investigations of Main Group Metal Complexes of Verdazyl Radicals Anderson K.J., *$Hicks R.G.
14:20 00914 Homogeneous and Bio-Catalysis in Concert: Hybrids of ECE-pincer Organometallics and Lipases van Koten G.
15:00 00915 Synthesis and Reactivity of a Phosphenium Cation Supported by a New BIAN Derivative Brazeau A.L., Caputo C.A., Jones N.D., *$Ragogna P.J.
15:20 00916 Exploring the Reactivity of NHC-stabilized Germylenes *Baines K.M., Rupar P.A., Ruddy A.J., Staroverov V.N.
15:40 Coffee Break
16:00 00917 Catena-Phosphinophosphonium Cations Knackstedt D., *Burford N., Carpenter Y., Conrad E., Weigand J., Robinson T., Whiorskey M.
16:20 00918 Development of Novel PCP and PBP Pincer Ligands Borau-Garcia J., Welsh P., Bosch M., *$Roesler R.
Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture - Monday, 17:00, Room 205 B D

17:00 End of Session

IN8Room 206 C

N-heterocyclic Carbene Chemistry

Organizer(s) - Dmitri Goussev
Chair(s) - S.K. Collins

13:40 00919 Carbenes and Carbones *$Frenking G.
14:20 00920 Synthesis and Applications of C(0)and N(I) Containing Compounds *$Alcarazo M.
14:40 00921 An N-Heterocyclic Diaminocarbene with a Ferrocenediyl-Backbone and its Reactivity towards Small Molecules Färber C., Bruhn C., Leibold M., *$Siemeling U., Frenking G.
15:00 00922 Donor Properties of N-Heterocyclic Carbenes and their MO Energies *$Gusev D.G.
15:20 00923 Macrocyclic and Supramolecular Chemistry with Poly-NHC Ligands *Hahn F.E.
15:40 Coffee Break
16:00 00924 Antimicrobial and Antitumor Properties of Silver(I) Carbene Complexes Encapsulated In Nanoparticles *$Youngs W.J., Cannon C.L., Tessier C.A., Yun Y., Panzner M.J., Robishaw N., Wright B., Knapp A., Besse D., Wagers P., Ditto A., Deblock M., Marshall W., Estes M., Leid J.
Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture - Monday, 17:00, Room 205 B D

16:40 End of Session

IN9Room 205 B D

Rings, Chains, and Polymers with Inorganic Elements

Organizer(s) - Daniel Foucher
Chair(s) - R. Morris

Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture

17:00 00925 Ancient Metals in Advanced Materials: Cyanoaurate-based Coordination Polymers Leznoff D.B.
17:40 End of Session

IN11Room 205 B D

Synthesis and Applications of Boron Compounds (joint with OR12)

Organizer(s) - Robert Batey; Cathleen Crudden

13:40 See OR12

Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture - Monday, 17:00, Room 205 B D

17:00 End of Session


Tuesday AM

IN2Room 205 A

Bioinorganic Chemistry (joint with BM1)

Organizer(s) - Deborah Zamble
Chair(s) - X. Zhang

08:40 See BM1

12:20 End of Session

IN5Room 206 C

Interplay of Ligand Design and Small Molecule Activation

Organizer(s) - Michael Fryzuk
Chair(s) - M.D. Fryzuk

08:20 01268 The Third Generation: Thousands of New Catalysts for Olefin Metathesis Schrock R.R.
09:00 01269 Activation of Small Molecules with a Silylamido NSiH...Mo Agostic Complex *Nikonov G.I.
09:20 01270 Small Molecule Reactivity of a Tantalaziridine-Hydride Complex Rankin M.A., $Cummins C.C.
09:40 01271 Capturing a Terminal Uranium Nitride by C-H Bond Activation Thomson R.K., Cantat T., Scott B.L., Morris D.E., Batista E.R., $Kiplinger J.L.
10:00 Coffee Break
10:20 01272 Will It Ever Be Possible to Make a Selective Ethylene Tetramerization Catalyst? *$Gambarotta S.
11:20 01274 Dinitrogen Activation by Group 4 & 5 Complexes Stabilised by o-Phenylene-Bridged Diamidophosphine Ligands *Hess F.M., Dimich A., Szlachetka T., $Fryzuk M.D.
11:40 01275 Cyclopentenyl Linked NPN Ligands and their Coordination Chemistry on Zr to Activate N2 Zhu T., *$Fryzuk M.D.
12:00 End of Session

IN6Room 206 A

Main Group Chemistry

Organizer(s) - Andrew McWilliams
Chair(s) - E. Rivard

08:00 01276 New Theoretical Insight into Bonding Interactions of the Group 13 Dimetallanes REER (E = Al-In, R = H, Me, tBu, and Ph) Moilanen J., *Tuononen H.M.
08:20 01277 Insights into Metal Borohydride Bonding: A Neutron Diffraction and Charge Density Study of [Na(15-crown-5)][BH4] *Sirsch P., Clark N., Onut L., Burchell R.P.L., Daoud-Aladine A., Gutmann M.J., $McGrady G.S.
08:40 01278 Organoborane Functionalized Conjugated Polymers: Toward New Optoelectronic and Sensory Materials *$Jaekle F., Li H., Sundararaman A., Chen P.
09:20 01279 Lewis Acid-Base Complexes of Aluminum Hydride Humphries T.D., *$McGrady G.S., Decken A., Munroe K., Sirsch P.
09:40 01280 Heteroleptic Amidinate Aluminum Hydrides: Synthesis, Thermal Profiling, and Vapour Deposition of Aluminum Metal Thin Films Delahunt J.R., $Barry S.T.
10:00 Coffee Break
10:20 01281 Late Transition Metal g3-Vinylborane Complexes: Borataallyl- and Alkyl/Borataalkene-Like Coordination Modes *$Emslie D.J. H., Kolpin K.B.
10:40 01282 Lewis Acid Catalyzed In Situ Polymerization of N-silylsulfonimidoyl Chlorides: An Ambient Temperature Route to Poly(oxothiazene)s *$McWilliams A.R., Aldeva V., Gezahegn S., Quinn J., Lough A.J.
11:00 01283 Catalytic Dehydrocoupling/Dehydrogenation Chemistry with Main Group Elements from Groups 13 and 15 Manners I.
11:40 01284 Capturing In+ Monomers in a Neutral Weakly Coordinating Environment Jurca T., *Gorelsky S.I., $Richeson D.S.
12:00 01285 Photochemical Stabilization of Tetrahedral Boron Chromophores by Metal Chelation Baik C., *Wang S.
12:20 End of Session

IN7Room 206 B

Nanochemistry (joint with OR7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - U.D. Hemraz; H. Fenniri

08:00 See OR7

12:20 End of Session

IN8Room 206 F

N-heterocyclic Carbene Chemistry

Organizer(s) - Dmitri Goussev
Chair(s) - C.M. Crudden

09:00 01286 NHC-Based Catalysts for Tandem Processes *$Peris E.
09:40 01287 Design, Synthesis and Catalytic Activity of Di-N-Heterocyclic Carbene Complexes of Nickel and Palladium Paulose T.A.P., *Quail J.W., $Foley S.R.
10:00 Coffee Break
10:20 01288 Highly Efficient Cross-Coupling of Aryl Chlorides and Hydrodechlorination Promoted by Pd-NHC Catalysts *$Cazin C.S.J.
11:00 01289 Carbene-Anchored, Pendent-Imidazolium Species as Precursors to Di-N-Heterocyclic Carbene-Bridged Mixed-Metal Complexes Zamora M.T., Ferguson M.J., McDonald R., *$Cowie M.
11:20 01290 Coordination Chemistry of Bidentate and Tridentate N-Aryl-Substituted Imino-N-Heterocyclic Carbene Ligands: Synthesis, Characterization and Coordination to Group 3-12 Transition Metals *$Lavoie G.G., Badaj A.C., Al Thagfi J., Larocque T., Dastgir S.
11:40 01291 Designing NHC-Transition Metal Complexes for C-C Bond Forming Reactions *$Collins S.K.
12:00 Reto Dorta

12:20 End of Session


Tuesday PM

IN1Room 206 F

Biodegradable / Green Polymers: Catalysis to Materials (joint with MS2)

Organizer(s) - Parisa Mehrkhodavandi
Chair(s) - P.G. Hayes

13:40 01565 Stereoselective Ring-Opening Polymerization of Lactide Using Lewis Acidic Metal Initiators *$Okuda J.
14:20 01566 Amine-Phenolate Metal Complexes for the Preparation of 'Green' Polymers *$Kerton F.M.
14:40 01567 Chiral Catalysts for the Polymerisation of rac-lactide Drouin F., Whitehorne T., Vabre B., *Schaper F.
15:00 01568 Chiral Indium Catalysts for the Enantioselective Polymerization of Cyclic Esters *$Mehrkhodavandi P., Acosta Ramirez J.A., Douglas A.F., Xu C., Duffy I.X., Yu J., Wallis C.
15:20 01569 Polymers Made from Renewable Resources: Crystallization and Morphology of Polylactides *$Prud'homme R.E., Wang X.
15:40 Coffee Break
16:00 01570 Biodegradable Polymer Stars: Control of Physical Properties and Degradation Rate *Shaver M.P., Cameron D.A. WITHDRAWN
16:20 01571 Design of Polymeric Nanoparticles for Protein Delivery to the Injured Spinal Cord Stanwick J.C., $Shoichet M.S.
16:40 01572 Tuning the Selectivity in Palladium-Catalyzed Butadiene Telomerization of Biopolymers Jabri A., *$Budzelaar P.H.M.
17:00 End of Session

IN2Room 205 A

Bioinorganic Chemistry (joint with BM1)

Organizer(s) - Deborah Zamble
Chair(s) - D. Zamble

14:00 See BM1

17:40 End of Session

IN5Room 206 C

Interplay of Ligand Design and Small Molecule Activation

Organizer(s) - Michael Fryzuk
Chair(s) - S. Gambarotta

13:40 01573 Macrocyclic Pacman Complexes - Tailored Molecular Clefts for Small Molecule Chemistry *Love J.B., Devoille A.M.J., Leeland J.W., Pecharman A.-F., Arnold P.L.
14:20 01574 Cofacial Pacman Macrocycles: Zinc Complexes and Anion Binding *Devoille A.M.J., Sessler J.L., $Love J.B.
14:40 01575 Structural and Reactivity Studies on Bimetallic Schiff-base Systems *$Storr T.
15:00 01576 Binuclear Metal Complexes Supported by Pincer Ligands Herbert D.E., *$Ozerov O.V.
15:20 01577 Application of N,N'-Disubstituted 1,8-Diamidonaphthalene Ligands with Early Transition Metal and Lanthanide Complexes Lavoie N., Kell T.J., Yap G.P. A,, Gorelsky S.I., *$Richeson D.S.
15:40 Coffee Break
16:00 01578 Activation and Redox Reactivity of Dioxygen and Other Oxidants at Copper and Cobalt Complexes from Fundamental to Applied Chemisty Sundermeyer J.
16:40 01579 Involvement of Amido/Imido Ligands in Oxygen-Atom Transfer Reactions Habibian M., *Ottenwaelder X.
17:00 01580 Design and Application of Novel C3-Symmetric Tridentate Sulfoxide Ligands Dornan P., Leung P., *$Dong V.M. WITHDRAWN
17:20 End of Session

IN7Room 206 B

Nanochemistry (joint with OR7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - J.M. Gibbs-Davis; A. Alsbaiee

13:40 See OR7

16:40 - 17:20 The Division of Inorganic Chemistry Award for Graduate Work Lecture

18:00 End of Session

IN9Room 206 A

Rings, Chains, and Polymers with Inorganic Elements

Organizer(s) - Daniel Foucher
Chair(s) - T. Baumgartner

13:40 01581 Organophosphorus Rings, Chains and Macromolecules *$Gates D.P.
14:00 01582 Synthetic Strategies, Thermal and Electrochemical Properties of Macromolecules Containing Transition Metals *$Abd-El-Aziz A.S., Shipman P.O., Winram D.J., Sezgin S., Rock C., Pilfold J.L.
14:20 01583 Strained Metallorings - New Reactivity and Utility as Metallopolymer Precursors Manners I.
15:00 01584 Strategies Toward Stable Polystannanes Foucher D., Komejan S., Khan A., Miles D.
15:20 01585 Modeling the Molecular and Electronic Structures of Oligostannanes *Wylie R.S., Khan A., Foucher D.A., Gossage R.A.
15:40 Coffee Break
16:00 01586 A Gallium-Bridged Polyferrocene with Observable Tacticity Bagh B., Gilroy J.B., Staubitz A., *$Müller J.
16:20 01587 Photocontrolled Living Anionic Polymerization of Phosphorus-Bridged [1]Ferrocenophanes Patra S.K., Whittell G.R., *Manners I.
16:40 01588 Ferrocene Based Metal-Chalcogenolates: Rings, Clusters and Coordination Polymers *$Corrigan J.F., MacDonald D.G., Ahmar S., Battista T.L., Taher D., Khalili B.
17:00 01589 Metallocalix[4]arene Containing g6-arene-g5-cyclopentadienyliron and Ferrocene Complexes Shipman P.O., *$Abd-El-Aziz A.S.
17:20 End of Session


Wednesday AM

IN1Room 206 F

Biodegradable / Green Polymers: Catalysis to Materials (joint with MS2)

Organizer(s) - Parisa Mehrkhodavandi
Chair(s) - F. Schaper

08:40 01731 Cationic Organozinc Lactide Polymerization Catalysts *$Hayes P.G., Wheaton C.A., McWilliams A.R.
09:00 01732 Group 3 Amidate Complexes for the Ring Opening Polymerization of Lactones Stanlake L.J.E., Thomson J., *$Schafer L.L.
09:20 01733 Tailor-made Polyesters via Metal-free Ring-opening Polymerization Thillaye du Boullay O., Bonduelle C., Martin-Vaca B., *Bourissou D.
10:00 Coffee Break
10:20 01734 Ring-Opening Reactions Involving Epoxides and Metal(III)porphyrin Complexes (M = Al, Cr, Co) *$Chisholm M.H.
11:00 01735 Complexes of Amine-bis(phenolate) Ligands as Initiators for Lactide Polymerization *$Kozak C.M.
11:20 01736 Carbon Dioxide Activation for the Synthesis of Polyethercarbonates Dienes Y., Erre G., Baruet J., Offermans W., Gürtler C., Müller T.E., Leitner W.
11:40 01737 Development of New Catalysts for the Synthesis of Biodegradable Polymeric Materials from Epoxides *Coates G.W.
12:20 End of Session

IN3Room 206 D

General

Organizer(s) - Robert Morris
Chair(s) - P. Kennepohl

08:00 01738 A Convenient Source of Cobalt(II) Dialkyl Fragments Zhu D., *Budzelaar P.H.M.
08:20 01739 Cobalt Alkyl Complexes as Self-initiating Mediators of Controlled Radical Polymerization Sherwood R.K., Sanders J.W., *$McNeil W.S.
08:40 01740 Synthesis and Structure of Mono- and Trimetallic Cobalt(II) Complexes of Amine-bis(phenolate) Ligands Das U.K., *Kerton F.M., $Kozak C.M.
09:00 01741 Exploring Reversible Chromium-Alkyl Bond Homolysis with CpCr(Nacnac)R Complexes $Smith K.M., MacLeod K.C.
09:20 01742 Monometallic, Bimetallic, and Organometallic Cr Complexes of Amine-bis(phenolate) Ligands Dean R.K., *$Kozak C.M.
09:40 01743 Cationic Manganese Phosphine Catalysts for Amine-Borane Dehydrogenation Burchell R., Rachiero G.P., Kivi C., $Baker R.T.
10:00 Coffee Break
10:20 01744 Negatively Charged Linkers for Neutral Metal-Organic Rotaxane Frameworks Vukotic N.V., $Loeb S.J.
10:40 01745 An Improved Precursor for Palladium(0) Cross-Coupling Catalysts Fraser A. W., Hull L.E., *$Baird M.C.
11:00 01746 Multiple C-H Bond Activations Promoted By Adjacent Iridium/Ruthenium Metal Centers *$Cowie M., Ulmer T.J., McDonald R., Ferguson M.J., Samant R.G., Trepanier S.J., Dutton J.L.
11:20 01747 The Fluoride Ion Donor-Acceptor and Lewis Acid Properties of ReO3F Ivanova M.V., Hughes M.J., Mercier H.P. A., *$Schrobilgen G.J.
11:40 01748 Mechanisms of Carbonyl Hydrosilylation Catalyzed by (Cp)(ArN)Mo(H)(PMe3) and (Tp)(ArN)Mo(H)(PMe3) Shirobokov O.G., $Nikonov G.I.
12:00 01749 Multiple Si-H Bond Activations in Mixed Rh/Ir Complexes Mobarok M.H., Oke O., McDonald R., Ferguson M., *$Cowie M.
12:20 End of Session

IN4Room 205 A

Inorganic Elements in the Environment (joint with EN4)

Organizer(s) - S.C. Mojumdar; J. Cutler
Chair(s) - S.C. Mojumdar; J. Cutler

08:00 See EN4

12:20 End of Session

IN5Room 206 C

Interplay of Ligand Design and Small Molecule Activation

Organizer(s) - Michael Fryzuk
Chair(s) - M. Stradiotto

08:20 01750 Simple Routes from P4 to Functional Organophosphorus Compounds *$Grützmacher H., Puschmann F., Ott T., Stein D., Alidori S.
09:00 01751 Ligand Design Challenges in the Activation of C-H and C-F bonds by Nickel: Towards Selective Catalytic Functionalization of Fluorinated Aromatics *$Johnson S.A.
09:20 01752 Bridging Organosilyl/Silylene Ligands in Mono-, Di- and Tetranuclear Nickel Complexes with Agostic Ni-H-Si Interactions Beck R., $Johnson S.A.
09:40 01753 New Binuclear Complexes with Multidentate, Hemilabile N,S-Ligands *$Bierenstiel M., Brown A., Cross E., Shehzad U., McLellan B., Foster D., Ferguson M.J.
10:00 Coffee Break
10:20 01754 Late Transition Metal Complexes Featuring Silyl Pincer Ligation: Applications in Challenging Bond Cleavage Reactions *$Turculet L.
11:00 01755 Ambiphilic Molecules as Ligands for Transitions Metals or for Interaction with Small Molecules Boudreau J., *Fontaine F.-G.
11:20 01756 Catalytic H2O Oxidation by Mononuclear Ru Complexes Wasylenko D.J., Ganesamoorthy C., Koivisto B.D., Henderson M.A., *$Berlinguette C.P.
11:40 01757 Electrochemical Reduction of CO2 with Novel Ruthenium(II) Complexes Chu J., Abedin T., Potvin P.G., Lever A.B.P.
12:00 End of Session

IN7Room 206 B

Nanochemistry (joint with OR7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - J. Rodriguez; J. Veinot

08:00 See OR7

12:20 End of Session

IN9Room 206 A

Rings, Chains, and Polymers with Inorganic Elements

Organizer(s) - Daniel Foucher
Chair(s) - D. Foucher

08:20 01758 New Approaches to Cyclic Selenium Imide Derivatives Eironen A., Risto M., Oilunkaniemi R., Takaluoma T., *$Laitinen R.S., Chivers T.
08:40 01759 Supramolecular Chemistry of Telluradiazoles: From Fundamental Bonding Studies to Functional Materials Cozzolino A.F., Elder P.J.W., Lee L.M., Yang Q., *Vargas-Baca I.
09:00 01760 Oligomerization in Dimethylthallium(III) Chalcogenolates [Me2TlER']n (E = O, S, Se) *$Briand G.G., Decken A., Hunter N.M., McKelvey J.I., Zhou Y.
09:20 01761 Synthesis, Structures and Properties of 1D-, 2D- and 3D- Polymeric Metal Arene-Chalcogenolato Complexes *$Eichhoefer A.
09:40 01762 Electrochemistry and EPR Spectroscopy of Phosphorus-Nitrogen Rings and Cages *$Boeré R.T., Roemmele T.L., Majoral J.-P., Sournia-Saquet A., Zablocka M.
10:00 Coffee Break
CCUCC Chemistry Doctoral Award Lecture

10:20 01763 From Poison to Pepto: The Role of the Metal Cation in Birefringent Cyanoaurate-containing Coordination Polymers Katz M.J., *Leznoff D.B.
11:00 01764 Synthesis of Reactive Molecules and Functional Polymers Using Inorganic Chemistry *$Rivard E., Thimer K., Al-Rafia S.M.I., Lummis P., Malcolm A.C., Kang L., Ferguson M.J., McDonald R.
11:20 01765 Dynamic Ring-Opening Polymerization of Transition Metal Complexes *$Puddephatt R.J.
12:00 01766 Design and Applications of 1D Polymers Using Tetrahedral Metallic Motifs and Bridging Ligands *$Harvey P.D., Jugé S., Knorr M., Leclerc M.
12:20 End of Session


Wednesday PM

IN1Room 206 F

Biodegradable / Green Polymers: Catalysis to Materials (joint with MS2)

Organizer(s) - Parisa Mehrkhodavandi
Chair(s) - P. Mehrkhodavandi

13:40 01883 Switchable Surfactants for the Preparation of Polymers Jessop P.G., Cunningham M.F.
14:20 01884 Enzyme-Mediated Silicon Chemistry: Green Routes to Silicon-Based Polymeric Materials Frampton M.B., Arnelien K., Subczynska I.T., *$Zelisko P.M.
14:40 01885 Synthesis of New Hybrid Mineral / Renewable Sol-Gel Matrices by Inter-Cross-Linking Siloxane Based Polymers with Polysaccharides *$Bliard C., Vreugdenhil A.J.
15:00 01886 Using Supercritical Fluids to Produce Nanomaterials and Nanodevices *$Charpentier P.A.
15:40 End of Session

IN3Room 206 D

General

Organizer(s) - Robert Morris
Chair(s) - P.H.M. Budzelaar

13:40 01887 Rhodium and Iridium Silyl Pincer Complexes: Applications in N-H Bond Activation Morgan E., $Turculet L.
14:00 01888 CH Bond Activation by Ni(0) Bis(phosphine) Complexes: A Mechanistic and Theoretical Study of Rapid CH and Slow CF Activation Hatnean J.A., $Johnson S.A.
14:20 01889 Exploration of Electronic Properties of Singlet Dioxygen as a Ligand in Rh(I) Complexes Covelli D., *$Kennepohl P.
14:40 01890 Novel Chiral Phosphonium Indenylide Complexes of Titanium and Ruthenium Fowler K.G., Littlefield S.L., Sonnenberg J.F., *$Baird M.C.
15:00 01891 Reactivity of Diamido-Actinide Organometallic Complexes Hayes C.E., *$Leznoff D.B.
15:20 01892 Scorpionates Complexes - Towards an Electrochemical Switch? $Vachon J., Mayoral M., Aymé-Perrot D., Soldera A., *Schougaard S.B.
15:40 Coffee Break
16:00 01893 Selective Oxidative Addition Reactions of Fluorinated Aromatics with Ni(0) and a Nitrogen Ancillary Ligand Doster M.E., *Johnson S.A.
16:20 01894 Inclusion Compounds with Low-Dimensional Metal Complexes or Lower Peptides as the Molecules of Host: Control Over Self-Assembly Through a Systematic Variation of Molecular Constituents *Soldatov D.V., Okeke E.B., Brown C.T., Yazdani A., Chirmanov V.V.
16:40 01895 Exploitation of p-Donor Substituents Dyker C.A.
17:00 End of Session

IN4Room 205 A

Inorganic Elements in the Environment (joint with EN4)

Organizer(s) - S.C. Mojumdar; J. Cutler
Chair(s) - D. Peak; M. Melnik

13:40 See EN4

15:20 End of Session

IN5Room 206 C

Interplay of Ligand Design and Small Molecule Activation

Organizer(s) - Michael Fryzuk
Chair(s) - J. Love

13:40 01896 Exploiting P,N-Ligands for the Palladium-Catalyzed Cross-coupling of Aryl chlorides and Amines: Broad Substrate Scope, Chemoselectivity, and Novel Room Temperature Ammonia Arylation Chemistry *$Stradiotto M.
14:20 01897 Enatiomerically Pure Phosphaalkene Based Ligands for Use in Asymmetric Allylic Alkylation Dugal-Tessier J., Dake G.R., Gates D.P.
14:40 01898 A Return to the Iron Age: C-C Cross-coupling Using Amine-bis(phenolate) Iron Complexes *$Kozak C.M.
15:00 01899 Asymmetric Lithiation of BF3-Activated Aminoferrocenes: Synthesis and Applications of Enantiopure Ligands Van Belle L., Zaifman J., *Metallinos C.
15:20 01900 Novel Phosphinimine Based Pincer Complexes: Coordination Chemistry and Reactivity Cariou R., Graham T. W., Dahcheh F., $Stephan D.W.
15:40 Coffee Break
16:00 01901 Electronic and Steric Effects of Ligands on the Activity of Iron Catalysts *$Morris R.H., Mikhailine A.A., Lagaditis P.O., Sues P., Lough A.J., Meyer N.
16:40 01902 Metal-Ligand Bifunctional Homogeneous Ionic Hydrogenation by a Ruthenium(II) Complex containing 6,6'-Diamino-2,2'-bipyridine Di Mondo D., *$Schlaf M. WITHDRAWN
17:00 01903 Dinitrogen Activation at an Electron-rich Ruthenium Centre Blacquiere J.M., Gorelsky S.I., $Fogg D.E.
17:20 01904 Hemilability, Catalysis and Diverse Coordination Chemistry of ortho-Phosphinoaniline Complexes of Rhodium and Ruthenium Hounjet L.J., Bierenstiel M., Ferguson M.J., McDonald R., *$Cowie M.
17:40 01905 Ligand-based Binding of Alkenes and 1,3-Dienes to Metal Dithiolenes: Production of New Ligands and Activation of Sulfur Heterocycles *$Fekl U., Harrison D.J., Nguyen N., Kerr M.J., Gapinska A.
18:00 End of Session

IN7Room 206 B

Nanochemistry (joint with OR7)

Organizer(s) - Hicham Fenniri; Jonathan Veinot
Chair(s) - M. Johnson

13:40 See OR7

15:40 End of Session

IN9Room 206 A

Rings, Chains, and Polymers with Inorganic Elements

Organizer(s) - Daniel Foucher
Chair(s) - E. Rivard

13:40 01906 Asymmetric Phosphorus-based Heterotetracene: A Versatile Core Towards N-type Semiconducting Materials Ren Y., *$Baumgertner T.
14:00 01907 Towards Dithienophosphole-based Molecular Dyes for Dye-Sensitized-Solar Cells Gordon T.J., Henderson M.A., Berlinguette C.P., *$Baumgartner T.
14:20 01908 Multimetallic Macrocycles: En Route to Molecule-Based Nanotubes Frischmann P.D., Guieu S., *$MacLachlan M.J.
15:00 01909 Hexatomic, Boat-Shaped, Cross-Linked, Bis(iminophosphorano)methanediide Pincer Carbon Bridged Photoluminescent Copper Clusters Capped with Methyl or Halide Bridges *$Cavell R.G., Ma G.-B., Ferguson M.J., McDonald R.
15:20 01910 Transition Metal Hydrazides for Kubas Type Hydrogen Storage *$Antonelli D.M., Hoang T.K.A., Hamaed A., Trudeau M.E., Hung M.V.
15:40 Coffee Break
16:00 01911 Characterization of High Order Ruthenium Chloride Clusters from a Stable "Sugar-Coated" Ruthenium-blue Solution by MALDI-TOF-MS Boncheff A.G., $Monteiro M.A.
16:20 01912 Dimerization Equilibria of Dibutyltin Dialkoxides in the Presence and Absence of Fluoride Whittleton S.R., Forget S., Boyd R.J., *$Grindley T.B.
16:40 01913 Cationic Zinc Species as Highly Active Catalysts for the Polymerization of Lactide Wheaton C.A., $Hayes P.G.
17:00 End of Session


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